1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

Base Information

Chemical Name:1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester
CAS No.:1423700-75-7
Molecular Formula:C₂₃H₂₇BO₄
Molecular Weight:378.276
Hs Code.:

Synonyms:1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:: 98%+ ^*data from raw suppliers

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Technology Process of 1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

There total 10 articles about 1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 2-(4-bromophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

: 1396007-85-4
1-[4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-cyclopropanecarboxylic acid methyl ester

: 1423700-75-7
1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

Guidance literature:: With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; water; In tetrahydrofuran; at 90 ℃; for 24h; chemoselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1002/chem.201500970

Reference yield: 78.0%

: 1-(4'-trifluoromethanesulfonyloxy-biphenyl-4-yl)cyclopropane-carboxylic acid methyl ester

: 73183-34-3
bis(pinacol)diborane

: 1423700-75-7
1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 25 - 90 ℃; for 16h;

Reference yield: 76.0%

: 1423700-73-5
methyl 1-[4-(4-bromophenyl)phenyl]cyclopropanecarboxylate

: 73183-34-3
bis(pinacol)diborane

: 1423700-75-7
1-[4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-4-yl]-cyclopropanecarboxylic acid methyl ester

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; Reflux; Inert atmosphere;