(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

Base Information

Chemical Name:(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate
CAS No.:1027785-12-1
Molecular Formula:C₃₉H₅₄N₂O₄SSi
Molecular Weight:675.02
Hs Code.:

Synonyms:(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

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Chemical Property of (3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

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Technology Process of (3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

There total 1 articles about (3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1027785-11-0
(3S,4R,5S)-allyl 4-[(S)-2-(tert-butoxycarbonylamino)-3-(tritylthio)propanamide]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

: 1027785-12-1
(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

Guidance literature:: With 2,6-dimethylpyridine; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1039/b718310k

Reference yield: 94.0%

: 1027785-35-8
(R)-2-[(S,E)-3-(4-methoxybenzyloxy)-7-(tritylthio)hept-4-enamido]propanoic acid

: 1027785-12-1
(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

: 1027785-37-0
(3S,4R,5R)-allyl 3-(tert-butyldimethylsiloxy)-4-[(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-(tritylthio)propionylamino]-5-methylheptanoate

Guidance literature:: With 1-hydroxy-7-aza-benzotriazole; N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; In dichloromethane; at -30 ℃; for 2h;
DOI:10.1039/b718310k

Reference yield: 92.0%

: 1027785-12-1
(3S,4R,5S)-allyl 4-[(S)-2-amino-3-(tritylthio)propanamido]-3-(tert-butyldimethylsilyloxy)-5-methylheptanoate

: 1581266-95-6
(R)-2-[(S,E)-3-(4-methoxybenzyloxy)-7-(tritylthio)hept-4-enamide]-4-(methylthio)butanoic acid

: (3S,4R,5R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-(4-methoxybenzyloxy)-7-(tritylthio)hept-4-enoylamino]-4-(methylthio)butanoylamino]-3-tritylthio(propionylamino)}-5-methylheptanoate

Guidance literature:: With 1-hydroxy-7-aza-benzotriazole; N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; In dichloromethane; at -30 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.ejmech.2014.02.044