phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside

Base Information

• Chemical Name: phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside
• CAS No.: 735326-98-4
• Molecular Formula: C₂₆H₂₆O₅S
• Molecular Weight: 450.555
• Mol file: 735326-98-4.mol

Synonyms:phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside

Chemical Property of phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside

There total 7 articles about phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

benzaldehyde dimethyl acetal (1125-88-8) + phenyl 3-O-benzyl-1-thio-α-L-idopyranoside (175978-39-9) → phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside (735326-98-4)

Guidance literature:

With camphor-10-sulfonic acid; at 50 ℃; for 3h; under 300.03 Torr;

DOI:10.1016/j.carres.2007.12.015

Reference yield: 46.0%

benzaldehyde dimethyl acetal (1125-88-8) + phenyl 3-O-benzyl-1-thio-L-idopyranoside (781657-63-4) → phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside (735326-98-4) + phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-β-L-idopyranoside (735327-19-2)

Guidance literature:

In N,N-dimethyl-formamide; at 70 ℃; for 5h; under 75.006 Torr;

DOI:10.1016/j.carres.2004.03.006

Reference yield: 46.0%

→ phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside (735326-98-4) + phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-β-L-idopyranoside (735327-19-2)

Guidance literature:

upstream raw materials:

benzaldehyde dimethyl acetal

phenyl 3-O-benzyl-1-thio-α-L-idopyranoside

phenyl 3-O-benzyl-1-thio-L-idopyranoside

thiophenol

Downstream raw materials:

phenyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-α-L-idopyranoside

3-O-(2-O-acetyl-α-L-idopyranosyl)-2,5-anhydro-1,6-di-O-benzoyl-D-mannitol

C₃₄H₄₆O₁₃Si

3-O-(2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-L-idopyranosyl)-2,5-anhydro-1,6-di-O-benzoyl-D-mannitol