methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

Base Information

Chemical Name:methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate
CAS No.:339540-27-1
Molecular Formula:C₁₇H₂₁ClO₆
Molecular Weight:356.803
Hs Code.:

Synonyms:methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

There total 5 articles about methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 67-56-1
methanol

: 339540-26-0
2,5-anhydro-6-O-benzyl-1,1-dichloro-1-deoxy-3,4-O-isopropylidene-D-ribo-hex-1-enitol

: 339540-27-1
methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

: 392743-12-3
methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hexofuranosonate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; at 24 ℃; for 0.266667h;
DOI:10.1016/S0008-6215(01)00239-7

Reference yield:

: 30725-00-9
2,3-O-isopropylidene-D-ribonic-γ-lactone

: 339540-27-1
methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / NaH / dimethylformamide

2: 7.5 percent / P(NMe₂)3 / CH₂Cl₂

3: 54 percent / 4-chloroperoxybenzoic acid; hydroquinone / CH₂Cl₂ / 16 h / 20 °C

With p-chloroperbenzoic acid; sodium hydride; hydroquinone; Hexamethylphosphorous triamide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(02)00217-3

Reference yield:

: 85846-80-6
5-O-benzyl-2,3-O-isopropylidene-D-ribono-1,4-lactone

: 339540-27-1
methyl 2,5-anhydro-6-O-benzyl-2-chloro-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hexofuranosonate

Guidance literature:: Multi-step reaction with 2 steps

1: 7.5 percent / P(NMe₂)3 / CH₂Cl₂

2: 54 percent / 4-chloroperoxybenzoic acid; hydroquinone / CH₂Cl₂ / 16 h / 20 °C

With p-chloroperbenzoic acid; hydroquinone; Hexamethylphosphorous triamide; In dichloromethane;
DOI:10.1016/S0008-6215(02)00217-3