[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

Base Information

Chemical Name:[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone
CAS No.:426820-55-5
Molecular Formula:C₅₄H₅₆O₈
Molecular Weight:833.034
Hs Code.:

Synonyms:[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

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Chemical Property of [4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

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Technology Process of [4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

There total 19 articles about [4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 426820-48-6
[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanol

: 426820-55-5
[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

Guidance literature:: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dimethyl sulfoxide; toluene; at 20 ℃;
DOI:10.1016/S0040-4039(01)02137-2

Reference yield:

: 100-39-0
benzyl bromide

: 426820-55-5
[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

Guidance literature:: Multi-step reaction with 11 steps

1: 96 percent / K₂CO₃ / dimethylformamide / 20 °C

2: mCPBA / CH₂Cl₂ / 20 °C

3: HCl / methanol / 20 °C

4: 84 percent / Br₂ / CHCl₃ / 20 °C

5: 80 percent / K₂CO₃ / dimethylformamide / 20 °C

6: 73 percent / 160 °C

7: 87 percent / K₂CO₃ / dimethylformamide / 20 °C

8: 95 percent / OsO₄; NaIO₄ / H₂O; diethyl ether / 20 °C

9: 72 percent / nBuLi / tetrahydrofuran / 0 °C

10: 49 percent / sBuLi / tetrahydrofuran / -78 °C

11: 76 percent / IBX / toluene; dimethylsulfoxide / 20 °C

With hydrogenchloride; sodium periodate; osmium(VIII) oxide; n-butyllithium; bromine; sec.-butyllithium; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform; water; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; 2: Baeyer-Villiger oxidation / 3: Baeyer-Villiger oxidation / 6: Claisen rearrangement / 8: Lemieux-Johnson oxidation / 9: Wittig reaction;
DOI:10.1016/S0040-4039(01)02137-2

Reference yield:

: 6195-80-8
2,4-bis(benzyloxy)phenol

: 426820-55-5
[4,6-bis-benzyloxy-2-methoxymethoxy-3-(3-methyl-but-2-enyl)-phenyl]-[4,6-bis-benzyloxy-3-methoxy-2-(3-methyl-but-2-enyl)-phenyl]-methanone

Guidance literature:: Multi-step reaction with 8 steps

1: 84 percent / Br₂ / CHCl₃ / 20 °C

2: 80 percent / K₂CO₃ / dimethylformamide / 20 °C

3: 73 percent / 160 °C

4: 87 percent / K₂CO₃ / dimethylformamide / 20 °C

5: 95 percent / OsO₄; NaIO₄ / H₂O; diethyl ether / 20 °C

6: 72 percent / nBuLi / tetrahydrofuran / 0 °C

7: 49 percent / sBuLi / tetrahydrofuran / -78 °C

8: 76 percent / IBX / toluene; dimethylsulfoxide / 20 °C

With sodium periodate; osmium(VIII) oxide; n-butyllithium; bromine; sec.-butyllithium; potassium carbonate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; chloroform; water; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; 3: Claisen rearrangement / 5: Lemieux-Johnson oxidation / 6: Wittig reaction;
DOI:10.1016/S0040-4039(01)02137-2