[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

Base Information

Chemical Name:[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6
CAS No.:85553-10-2
Molecular Formula:C₃₂H₂₀Fe₂O₆S₂Sn
Molecular Weight:795.043
Hs Code.:

[SC(C<sub>6</sub>H<sub>5</sub>)C(Sn(C<sub>6</sub>H<sub>5</sub>)3)S]Fe<sub>2</sub>(CO)6

Synonyms:[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

Suppliers and Price of [SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

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Technology Process of [SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

There total 1 articles about [SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 14243-23-3
(μ-dithio)bis(tricarbonyliron)

: 639-58-7
triphenyltin chloride

: 536-74-3
phenylacetylene

: 85553-01-1
(CO)6Fe2(μ-SC(Ph)=C(H)S)

: 85553-10-2
[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N2-atmosphere; addn. of BuLi to PhC2H (-78°C), then stirring without cooling (1 h), addn. of Fe-complex (-78°C), stirring (30 min, -78°C), addn. of Ph3SnCl, stirring (15 min, -78°C; then 19 h, room temp.); solvent removal (reduced pressure), chromy. (silicic acid, pentane/CH2Cl2=4:1), crystn. (pentane/CH2Cl2); elem. anal.;

Reference yield: 59.0%

: 85553-10-2
[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

: (C₆H₅CCS)(CH₃S)Fe₂(CO)6

Guidance literature:: With phenyllithium; methyl iodide; In diethyl ether; complex treated with C6H5Li in Et2O at -78°C, treated with CH3I;

Reference yield: 50.0%

: 85553-10-2
[SC(C₆H₅)C(Sn(C₆H₅)3)S]Fe₂(CO)6

: 591-51-5
phenyllithium

: (C₆H₅CCS)(CH₃S)Fe₂(CO)6

: 595-90-4
tetraphenyltin(IV)

Guidance literature:: With methyl iodide; In diethyl ether; N2-atmosphere; stirring of Fe-complex and PhLi (-78°C, 1 h), MeIaddn., stirring (-78°C, 0.5 h; then room temp., 2 h); filtration off of Ph4Sn, solvent removal, chromy. (silicic acid, pentane); isomer mixt. not sepd., total yield 63%;