2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside
CAS No.:152252-35-2
Molecular Formula:C₄₅H₅₉NO₁₄Si
Molecular Weight:866.047
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

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Chemical Property of 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

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Technology Process of 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

There total 10 articles about 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: methyl 3,4-di-O-acetyl-2-(benzoyloxyimino)-1-bromo-2-deoxy-α-D-arabino-hexopyranuronate

: 152252-35-2
2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / silver aluminosilicate / CH₂Cl₂ / 2 h / Ambient temperature

2: 1.) BH₃-THF

With borane-THF; silver aluminosilicate; In dichloromethane;
DOI:10.1246/bcsj.67.1130

Reference yield:

: 152252-33-0
2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside

: 152252-35-2
2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / silver aluminosilicate / CH₂Cl₂ / 2 h / Ambient temperature

2: 1.) BH₃-THF

With borane-THF; silver aluminosilicate; In dichloromethane;
DOI:10.1246/bcsj.67.1130

Reference yield:

: 62346-09-2
methyl 2-acetoxy-3,4-di-O-acetyl-D-arabino-hex-1-enopyranuronate

: 152252-35-2
2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 56 percent / NH₂OH*HCl, Py / 20 h / Ambient temperature

2: 1.) Py, 2.) NBS / 1.) 3 h, 2.) CCl4, hν, reflux, 30 min

3: 88 percent / silver aluminosilicate / CH₂Cl₂ / 2 h / Ambient temperature

4: 1.) BH₃-THF

With pyridine; N-Bromosuccinimide; borane-THF; silver aluminosilicate; hydroxylamine hydrochloride; In dichloromethane;
DOI:10.1246/bcsj.67.1130