cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Base Information

• Chemical Name: cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)
• CAS No.: 107031-82-3
• Molecular Formula: C₄₅H₃₈O₂P₂RuS
• Molecular Weight: 805.879

Synonyms:cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Chemical Property of cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

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Technology Process of cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

There total 7 articles about cis,cis,trans-hydrido((pMeC₆H₄)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cis,cis,trans-hydrido(Cl)(carbonyl)2(triphenylphosphine)2ruthenium(II) (32240-58-7) + sodium p-thiocresolate (10486-08-5) → cis,cis,trans-hydrido((pMeC6H4)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-82-3) + cis,cis,trans-bis((pMe)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)*THF (136823-98-8)

Guidance literature:

In acetone; under Ar at 20°C overnight; vac. distn., (1)H and (31)P NMR detn.;

Reference yield: 12.0%

cis,cis,trans-dihydrido(carbonyl)2(triphenylphosphine)2ruthenium(II) (20574-17-8,21029-29-8,239076-83-6) + thiophenol (108-98-5) + para-thiocresol (106-45-6) → cis,cis,trans-bis((Ph)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (136890-88-5) + cis,cis,trans-hydrido((Ph)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107052-99-3) + cis,cis,trans-hydrido((pMeC6H4)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-82-3) + cis,cis,trans-bis((pMe)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)*THF (136823-98-8) + cis,cis,trans-((pMeC6H4)thiolato)((Ph)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (136823-96-6)

Guidance literature:

In benzene-d6; byproducts: PPh3; under Ar, react. in an NMR tube in soln. at 21°C for 7 h; (31)P NMR detn.;

Reference yield: 10.0%

cis,cis,trans-hydrido(Cl)(carbonyl)2(triphenylphosphine)2ruthenium(II) (32240-58-7) + sodium p-thiocresolate (10486-08-5) → tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7) + {ruthenium(0) dicarbonyltris(triphenylphosphine)} (35880-54-7,61647-76-5,184490-77-5,65635-71-4) + cis,cis,trans-hydrido((pMeC6H4)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-82-3) + cis,cis,trans-bis((pMe)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)*THF (136823-98-8) + triphenylphosphine (603-35-0)

Guidance literature:

In acetone; under Ar at 20°C for 2 h; vac. distn., (1)H and (31)P NMR detn.;

upstream raw materials:

{ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)}

di(p-tolyl) disulfide

para-thiocresol

cis-RuH₂(CO)2(PPh₃)2

Downstream raw materials:

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

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