C₂₃H₃₁IO₂Si

Base Information

Chemical Name:C₂₃H₃₁IO₂Si
CAS No.:1442433-11-5
Molecular Formula:C₂₃H₃₁IO₂Si
Molecular Weight:494.488
Hs Code.:

C<sub>23</sub>H<sub>31</sub>IO<sub>2</sub>Si

Synonyms:C₂₃H₃₁IO₂Si

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Chemical Property of C₂₃H₃₁IO₂Si

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Technology Process of C₂₃H₃₁IO₂Si

There total 1 articles about C₂₃H₃₁IO₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1007401-44-6
((2S,3S)-2-(4-(tert-butyldiphenylsilyloxy)butyl)oxiran-2-yl)methanol

: 1442433-11-5
C₂₃H₃₁IO₂Si

Guidance literature:: ((2S,3S)-2-(4-(tert-butyldiphenylsilyloxy)butyl)oxiran-2-yl)methanol; With 1H-imidazole; triphenylphosphine; In tetrahydrofuran; at 0 ℃; for 0.333333h; Inert atmosphere;

With iodine; In tetrahydrofuran; at 0 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1016/j.tet.2015.06.036

Reference yield:

: 1442433-11-5
C₂₃H₃₁IO₂Si

: 1434059-19-4
(S)-7-(tert-butyldiphenylsilyloxy)hept-1-en-3-ol

Guidance literature:: With sodium iodide; zinc; In ethanol; for 2h; Reflux;
DOI:10.1016/j.tetlet.2013.04.069

Reference yield:

: 1442433-11-5
C₂₃H₃₁IO₂Si

: C₂₈H₄₂O₉

Guidance literature:: Multi-step reaction with 10 steps

1.1: zinc; sodium iodide / ethanol / 2 h / Reflux

2.1: N-ethyl-N,N-diisopropylamine / 2 h / 20 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 20 °C

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 4 h / 20 °C

5.1: sodium chlorite; 2-methyl-but-2-ene; sodium dihydrogenphosphate / tetrahydrofuran; tert-butyl alcohol; water / 3 h / 0 - 20 °C

6.1: dmap; triethylamine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0.5 h / 0 °C

6.2: 12 h / 0 - 20 °C

7.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 36 h / Inert atmosphere; Reflux

8.1: diisobutylaluminium hydride / dichloromethane; toluene / -78 - 0 °C / Inert atmosphere

9.1: benzene / 8 h / 80 °C / Inert atmosphere

10.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 3 h / 0 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N-ethyl-N,N-diisopropylamine; sodium iodide; zinc; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; ethanol; dichloromethane; water; dimethyl sulfoxide; toluene; tert-butyl alcohol; benzene;
DOI:10.1016/j.tetlet.2013.04.069