1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

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Chemical Name:1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene
CAS No.:121221-38-3
Molecular Formula:C₂₃H₁₈Cl₂
Molecular Weight:365.302
Hs Code.:

Synonyms:1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

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Technology Process of 1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

There total 4 articles about 1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 515-84-4
Ethyl trichloroacetate

: 106032-13-7
1-(9-phenanthryl)-2-phenylethane

: 121221-38-3
1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

Guidance literature:: With sodium methylate; In pentane;
DOI:10.1002/hlca.19880710707

Reference yield:

: 17482-62-1
2-(9-phenanthryl)-1-phenylethanol

: 121221-38-3
1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / SOCl₂ / CHCl₃ / r.t., overnight, reflux, 5 h

2: 71 percent / NaBH₄ / dimethylsulfoxide / 80 °C

3: 71 percent / MeONa / pentane

With sodium tetrahydroborate; thionyl chloride; sodium methylate; In chloroform; dimethyl sulfoxide; pentane;
DOI:10.1002/hlca.19880710707

Reference yield:

: 4707-71-5
Phenanthrene-9-carboxaldehyde

: 121221-38-3
1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Mg / 1.) THF, 3 h, reflux; 2.) THF, 10 h, r.t.

2: 93 percent / SOCl₂ / CHCl₃ / r.t., overnight, reflux, 5 h

3: 71 percent / NaBH₄ / dimethylsulfoxide / 80 °C

4: 71 percent / MeONa / pentane

With sodium tetrahydroborate; thionyl chloride; sodium methylate; magnesium; In chloroform; dimethyl sulfoxide; pentane;
DOI:10.1002/hlca.19880710707