1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide

Base Information

• Chemical Name: 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide
• CAS No.: 1374036-99-3
• Molecular Formula: C₁₉H₂₈IN₂*I
• Molecular Weight: 538.254
• Mol file: 1374036-99-3.mol

Synonyms:1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide

Chemical Property of 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide

There total 2 articles about 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-Iodooctane (629-27-6) + 1-(4-iodophenyl)-4,5-dimethyl-1H-imidazole (1374036-95-9) → 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide (1374036-99-3)

Guidance literature:

In acetonitrile; at 70 ℃; for 336h; Inert atmosphere;

DOI:10.1039/c2dt12322c

Reference yield:

p-aminoiodobenzene (540-37-4) → 1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide (1374036-99-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: methanol / 16 h / 20 °C / Inert atmosphere

1.2: 2 h / Inert atmosphere; Reflux

2.1: acetonitrile / 336 h / 70 °C / Inert atmosphere

In methanol; acetonitrile;

DOI:10.1039/c2dt12322c

Reference yield: 63.0%

1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide (1374036-99-3) + diphenylphosphane (829-85-6) → 1-(4-(diphenylphosphino)phenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium hexafluorophosphate

Guidance literature:

1-(4-iodophenyl)-3-(n-octyl)-4,5-dimethyl-1H-imidazolium iodide; diphenylphosphane; With potassium acetate; palladium diacetate; In N,N-dimethyl acetamide; at 130 ℃; for 2h; Inert atmosphere;

With potassium hexafluorophosphate; In water; acetone; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c2dt12322c

upstream raw materials:

1-Iodooctane

1-(4-iodophenyl)-4,5-dimethyl-1H-imidazole

p-aminoiodobenzene