Technology Process of methyl 3-O-benzyl-L-fucopyranoside
There total 1 articles about methyl 3-O-benzyl-L-fucopyranoside which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrabutylammomium bromide; di(n-butyl)tin oxide; N-ethyl-N,N-diisopropylamine;
In
neat (no solvent);
at 70 ℃;
for 6h;
regioselective reaction;
DOI:10.1021/jo402399n
- Guidance literature:
-
Multi-step reaction with 4 steps
1: sodium hydride / dimethyl sulfoxide
2: acetic acid; acetic anhydride; trifluoroacetic acid / 0 - 20 °C
3: diethylamino-sulfur trifluoride / dichloromethane / -40 - 20 °C
4: lithium perchlorate; cesium fluoride / dichloromethane / -40 - 20 °C
With
diethylamino-sulfur trifluoride; lithium perchlorate; acetic anhydride; sodium hydride; acetic acid; cesium fluoride; trifluoroacetic acid;
In
dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2013.05.064
- Guidance literature:
-
Multi-step reaction with 6 steps
1: sodium hydride / dimethyl sulfoxide
2: acetic acid; acetic anhydride; trifluoroacetic acid / 0 - 20 °C
3: diethylamino-sulfur trifluoride / dichloromethane / -40 - 20 °C
4: lithium perchlorate; cesium fluoride / dichloromethane / -40 - 20 °C
5: (1,5-cyclooctadiene)[bis(methyldiphenylphosphine)]iridium(I) hexafluorophosphate / tetrahydrofuran
6: camphor-10-sulfonic acid / methanol; dichloromethane
With
(1,5-cyclooctadiene)[bis(methyldiphenylphosphine)]iridium(I) hexafluorophosphate; diethylamino-sulfur trifluoride; camphor-10-sulfonic acid; lithium perchlorate; acetic anhydride; sodium hydride; acetic acid; cesium fluoride; trifluoroacetic acid;
In
tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2013.05.064
