65310-00-1

Basic information

• Product Name: METHYL-L-FUCOPYRANOSIDE
• Synonyms: METHYL-L-FUCOPYRANOSIDE;METHYL A,B-L-FUCOPYRANOSIDE;Methyl-L-fucopyranoside,99+%;Methyl Fucopyranoside (an a, mixture containing approx. 70% beta);Methyl Fucopyranoside (an α,β mixture containing approx. 70% beta);Methyl 6-Deoxy-;Methyl Fucopyranoside (α,β Mixture)
• CAS NO: 65310-00-1
• Molecular Formula: C₇H₁₄O₅
• Molecular Weight: 178.18
• Product Categories: Carbohydrates & Derivatives
• Mol File: 65310-00-1.mol
• Article Data: 60

Chemical Properties

• Melting Point: 150-152°C
• Boiling Point: 230.4°C (rough estimate)
• Appearance: /
• Density: 1.1571 (rough estimate)
• Refractive Index: 1.4330 (estimate)
• Storage Temp.: 2-8°C
• Solubility: Chloroform (Slightly), Methanol (Slightly), Water (Slightly)
• PKA: 13.05±0.70(Predicted)
• CAS DataBase Reference: METHYL-L-FUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL-L-FUCOPYRANOSIDE(65310-00-1)
• EPA Substance Registry System: METHYL-L-FUCOPYRANOSIDE(65310-00-1)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 65310-00-1(Hazardous Substances Data)

Usage

Chemical Properties

White crystalline powder

Uses

Methyl Fucopyranoside (α,β mixture) (cas# 65310-00-1) is a compound useful in organic synthesis.

InChI:InChI=1/C7H14O5/c1-3-4(8)5(9)6(10)7(11-2)12-3/h3-10H,1-2H3/t3-,4+,5-,6-,7?/m0/s1

Upstream product

• 4148-58-7 (4aR,6S,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 2774-23-4 methyl 2-O-acetyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 26295-65-8 (4aR,6S,7S,8S,8aR)-7,8-Bis-(1-ethoxy-ethoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 53942-13-5 Methyl 2,3,4-Tri-O-acetyl-6-deoxy-β-D-galactopyranoside 
• 39981-26-5 methyl 6-deoxy-3,4-O-isopropylidene-β-D-galactopyranoside 
• 67-56-1 methanol 
• 1226-39-7 p-nitrophenyl-β-D-fucopyranoside 
• 14917-55-6 methyl 6-deoxy-α-L-mannopyranoside 
• 15814-59-2 (2S,3S,4S,5S,6R)-2-methoxy-6-methyltetrahydro-2H-pyran-3,4,5-triol 
• 73-34-7 6-deoxy-L-galactose 
• 75-36-5 acetyl chloride 
• 5155-46-4 methyl 6-deoxy-6-iodo-D-altroside 
• 1128-40-1 methyl β-L-fucopyranoside 
• 73-34-7 L-rhamnose 

Downstream Products

• 14064-39-2 L-galacto-2,4,5-Trihydroxy-3-methoxy-hexanal 
• 3615-37-0 D-Fucose 
• 56271-60-4 (3R,4R,5S,6S)-2-Methoxy-6-methyl-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran 
• 42214-01-7 methyl 2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 
• 101068-99-9 methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside 
• 15830-76-9 methyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-talopyranoside 
• 4860-85-9 methyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 112047-81-1 O³-methyl-L-lyxo-6-deoxy-[2]hexosulose-bis-phenylhydrazone 
• 14917-71-6 methyl-(O³,O⁴-isopropylidene-O²-methyl-β-L-fucopyranoside) 
• 152554-45-5 β-methyl 2,3,4-tri-O-(4-chlorobenzyl)-6-deoxy-L-galactopyranoside 
• 1379777-16-8 methyl 3-O-phenoxythiocarbonyl-β-L-fucopyranoside 
• 1399293-50-5 methyl 3-O-(3,5-difluorobenzensulfonyl)-β-L-fucopyranoside 
• 1447729-43-2 methyl 3-O-benzyl-L-fucopyranoside 

Relevant articles and documents

PROCESS FOR PRODUCING 2'-O-FUCOSYLLACTOSE

The present invention relates to a method for preparing 2′-O-fucosyllactose, the intermediates obtainable by this method and the use of these intermediates. The preparation comprises the reaction of a protected fucose of the general formula (I) with a tri

Synthesis of β-(1→2)-Linked 6-Deoxy- l -altropyranose Oligosaccharides via Gold(I)-Catalyzed Glycosylation of an ortho-Hexynylbenzoate Donor

The β-(1→2)-linked 6-deoxy-l-altropyranose di- to pentasaccharides 2-5, relevant to the O-antigen of the infectious Yersinia enterocolitica O:3, were synthesized for the first time. The challenging 1,2-cis-altropyranosyl linkage was assembled effectively via glycosylation with 2-O-benzyl-3,4-di-O-benzoyl-6-deoxy-l-altropyranosyl ortho-hexynylbenzoate (7) under the catalysis of PPh3AuNTf2. NMR and molecular modeling studies showed that the pentasaccharide (5) adopted a left-handed helical conformation.

Direct glycosylation of unprotected and unactivated sugars using bismuth nitrate pentahydrate

Bi(NO3)3, a low-cost, mild, and environmentally green catalyst, has been successfully utilized for Fischer glycosylation for the synthesis of alkyl/aryl glycopyranosides by reacting unprotected sugars, namely, D-glucose, L-rhamnose, D-galactose, D-arabinose, and N-acetyl-D-glucosamine with various alcohols in good to excellent yields. The glycosides were formed with high α-selectivity. Further, an expedient separation of α- and β-glycosides using silver nitrate-impregnated silica gel flash liquid chromatography has been developed.