N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

Base Information

Chemical Name:N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate
CAS No.:151915-24-1
Molecular Formula:C₂₈H₃₃NO₅Si
Molecular Weight:491.659
Hs Code.:

Synonyms:N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

Suppliers and Price of N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

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Technology Process of N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

There total 6 articles about N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5672-89-9
N-trifluoroacetoxy succinimide

: 151915-19-4
(S)-(-)-4-<(tert-Butyldiphenylsilyl)oxy>-5(E),7-octadienoic acid

: 151915-24-1
N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

Guidance literature:: With pyridine; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo00074a040

Reference yield:

: 75629-74-2
(S)-(-)-Tetrahydro-5-oxo-2-furancarboxaldehyde

: 151915-24-1
N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

Guidance literature:: Multi-step reaction with 6 steps

1: 86 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.5 h / -78 °C

2: 94 percent / potassium tert-butoxide / tetrahydrofuran / 0.25 h / Ambient temperature

3: tetrahydrofuran; methanol; H₂O / 0.5 h / Ambient temperature

4: imidazole, 4-DMAP / dimethylformamide / 72 h / Ambient temperature

5: 94 percent / LiOH*H₂O / tetrahydrofuran; methanol / 0.25 h / Ambient temperature

6: 100 percent / pyridine / tetrahydrofuran / Ambient temperature

With pyridine; 1H-imidazole; dmap; lithium hydroxide; boron trifluoride diethyl etherate; potassium tert-butylate; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00074a040

Reference yield:

: 151915-16-1
(S)-(+)-Dihydro-5-<(E)-1,3-butadienyl>-2(3H)-furanone

: 151915-24-1
N-Succinimidyl 4(S)-<(tert-butyldiphenylsilyl)oxy>-5(E),7-octadienoate

Guidance literature:: Multi-step reaction with 4 steps

1: tetrahydrofuran; methanol; H₂O / 0.5 h / Ambient temperature

2: imidazole, 4-DMAP / dimethylformamide / 72 h / Ambient temperature

3: 94 percent / LiOH*H₂O / tetrahydrofuran; methanol / 0.25 h / Ambient temperature

4: 100 percent / pyridine / tetrahydrofuran / Ambient temperature

With pyridine; 1H-imidazole; dmap; lithium hydroxide; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00074a040