4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

Base Information

Chemical Name:4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2
CAS No.:205489-41-4
Molecular Formula:C₂₈H₃₈O₄Si
Molecular Weight:468.677
Hs Code.:

Synonyms:4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

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Technology Process of 4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

There total 2 articles about 4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: triisopropylsilyl trifluoromethanesulfonate

: 205489-56-1
4-phenyl-3-hydroxy-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

: 205489-41-4
4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane;
DOI:10.1021/ja962933u

Reference yield:

: 98-86-2
acetophenone

: 205489-41-4
4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Li-HMDS / 1.) THF, -78 deg C, 45 min, 2.) THF, 20 min

2: 76 percent / 2,6-lutidine / CH₂Cl₂

With 2,6-dimethylpyridine; lithium hexamethyldisilazane; In dichloromethane;
DOI:10.1021/ja962933u

Reference yield:

: 205489-41-4
4-phenyl-3-[(triisopropylsilyl)oxy]-1-(4-methyl benzoate)-4-penten-1-one-5,5-d2

: 2-(4-benzoic acid)-3-hydroxy-5-phenyl-1,5-hexadiene-1,1,6,6-d4

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, 0 deg C, 45 min, 2.) THF, from 0 deg C to 20 deg C, 0.5 h

2: tetra-n-butylammonium fluoride / tetrahydrofuran / 0 °C

3: aq. KOH / dioxane / 3 h / Ambient temperature

With potassium hydroxide; n-butyllithium; tetrabutyl ammonium fluoride; In tetrahydrofuran; 1,4-dioxane;
DOI:10.1021/ja962933u