(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

Base Information

Chemical Name:(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene
CAS No.:924661-31-4
Molecular Formula:C₂₂H₃₆OSi
Molecular Weight:344.613
Hs Code.:

Synonyms:(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

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Chemical Property of (SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

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Technology Process of (SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

There total 3 articles about (SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: rac-1-chloro-1-isopropyl-(1,2,3,4-tetrahydro)-1-silanaphthalene

: 2216-51-5
(-)-menthol

: 924661-31-4
(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

: (SiR)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

Guidance literature:: (-)-menthol; With potassium hydride; In tetrahydrofuran; for 1h; Heating;

rac-1-chloro-1-isopropyl-(1,2,3,4-tetrahydro)-1-silanaphthalene; In tetrahydrofuran; for 4h; Heating;
DOI:10.1021/ja067780h

Reference yield:

: 924661-29-0
rac-1-isopropyl-(1,2,3,4-tetrahydro)-1-silanaphthalene

: 924661-31-4
(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

Guidance literature:: Multi-step reaction with 2 steps

1.1: Cl₂ / CCl₄ / 0.07 h / 0 °C

2.1: potassium hydride / tetrahydrofuran / 1 h / Heating

2.2: 33 percent / tetrahydrofuran / 4 h / Heating

With chlorine; potassium hydride; In tetrahydrofuran; tetrachloromethane;
DOI:10.1021/ja067780h

Reference yield:

: 1075-28-1
1-bromo-2-(3-bromopropyl)benzene

: 924661-31-4
(SiS)-1-isopropyl-1-[(1R,2S,5R)-1-menthyloxy]-1,2,3,4-tetrahydro-1-silanaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1.1: magnesium; 1,2-dibromoethane / tetrahydrofuran / 14 h / Heating

1.2: 43 percent / LiAlH₄ / tetrahydrofuran / 3 h / Heating

2.1: Cl₂ / CCl₄ / 0.07 h / 0 °C

3.1: potassium hydride / tetrahydrofuran / 1 h / Heating

3.2: 33 percent / tetrahydrofuran / 4 h / Heating

With chlorine; potassium hydride; magnesium; ethylene dibromide; In tetrahydrofuran; tetrachloromethane;
DOI:10.1021/ja067780h