C₄₄H₄₈F₃N₃O₁₀SSi

Base Information

Chemical Name:C₄₄H₄₈F₃N₃O₁₀SSi
CAS No.:203922-35-4
Molecular Formula:C₄₄H₄₈F₃N₃O₁₀SSi
Molecular Weight:896.026
Hs Code.:

C<sub>44</sub>H<sub>48</sub>F<sub>3</sub>N<sub>3</sub>O<sub>10</sub>SSi

Synonyms:C₄₄H₄₈F₃N₃O₁₀SSi

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Chemical Property of C₄₄H₄₈F₃N₃O₁₀SSi

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Technology Process of C₄₄H₄₈F₃N₃O₁₀SSi

There total 27 articles about C₄₄H₄₈F₃N₃O₁₀SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111726-43-3
3,4-(methylenedioxy)phenyl methoxymethyl ether

: 203922-35-4
C₄₄H₄₈F₃N₃O₁₀SSi

Guidance literature:: Multi-step reaction with 21 steps

1: 1.) BuLi, tetramethylethylene diamine / 1.) hexane, 0 deg C, 4 h, 2.) hexane, from -78 deg C to 23 deg C, 15 min

2: 1.) BuLi / 1.) THF, -30 deg C, 13 h

3: CH₃SO₃H / CH₂Cl₂ / 0 °C

4: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) DMF, 23 deg C, 40 min

5: 99 percent / piperidine, acetic acid / benzene / 18 h / 23 °C

6: 94 percent / Et₃N, HCOOH, Pd(PPh₃)4 / 4 h / 23 °C

7: (PhO)2P(O)N₃, Et₃N, 4 Angstroem molecular sieves / toluene / 2 h / 70 °C

8: 1 h / 23 °C

9: 97 percent / H₂, Rh<(COD)-(R,R)-DIPAMP>(+)*BF₄(-) / 16 h / 23 °C / 2280 Torr

10: BF₃*Et₂O, H₂O / CH₂Cl₂ / 0.17 h / 0 °C

11: BF₃*Et₂O, 4 Angstroem molecular sieves / CH₂Cl₂ / 18 h / 23 °C

12: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 6 h / 23 °C / 760 Torr

13: 61 percent / HOAc / 18 h / 23 °C

14: 87 percent / Cs₂CO₃ / dimethylformamide / 1 h / 23 °C

15: diisobutylaluminum hydride / toluene / 5 h / -78 °C

16: KF*2H₂O / methanol / 0.33 h / 23 °C

17: CH₃SO₃H, 3 Angstroem molecular sieves / CH₂Cl₂ / 5 h / 23 °C

18: 72 percent / Et₃N, DMAP / CH₂Cl₂ / 6 h / 23 °C

19: 89 percent / DMAP / CH₂Cl₂ / 13 h / 23 °C

20: 92 percent / i-Pr₂NEt / CH₂Cl₂ / 0.33 h / 23 °C

21: 1.) Bu₃SnH, PdCl₂(PPh₃)2, HOAc, 2.) NaBH₃CN, HOAc / 1.) CH₂Cl₂, 23 deg C, 15 min, 2.) CH₃CN, 23 deg C, 30 min

With piperidine; dmap; bis-triphenylphosphine-palladium(II) chloride; potassium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; formic acid; methanesulfonic acid; N,N,N,N,-tetramethylethylenediamine; Rh<(COD)-(R,R)-DIPAMP>(+)*BF4(-); 3 A molecular sieve; 4 A molecular sieve; diphenyl phosphoryl azide; boron trifluoride diethyl etherate; water; hydrogen; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; sodium cyanoborohydride; caesium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ja962480t

Reference yield:

: 187040-02-4
5-methoxy methoxy-4-methyl benzo[d][1,3]dioxole

: 203922-35-4
C₄₄H₄₈F₃N₃O₁₀SSi

Guidance literature:: Multi-step reaction with 20 steps

1: 1.) BuLi / 1.) THF, -30 deg C, 13 h

2: CH₃SO₃H / CH₂Cl₂ / 0 °C

3: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) DMF, 23 deg C, 40 min

4: 99 percent / piperidine, acetic acid / benzene / 18 h / 23 °C

5: 94 percent / Et₃N, HCOOH, Pd(PPh₃)4 / 4 h / 23 °C

6: (PhO)2P(O)N₃, Et₃N, 4 Angstroem molecular sieves / toluene / 2 h / 70 °C

7: 1 h / 23 °C

8: 97 percent / H₂, Rh<(COD)-(R,R)-DIPAMP>(+)*BF₄(-) / 16 h / 23 °C / 2280 Torr

9: BF₃*Et₂O, H₂O / CH₂Cl₂ / 0.17 h / 0 °C

10: BF₃*Et₂O, 4 Angstroem molecular sieves / CH₂Cl₂ / 18 h / 23 °C

11: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 6 h / 23 °C / 760 Torr

12: 61 percent / HOAc / 18 h / 23 °C

13: 87 percent / Cs₂CO₃ / dimethylformamide / 1 h / 23 °C

14: diisobutylaluminum hydride / toluene / 5 h / -78 °C

15: KF*2H₂O / methanol / 0.33 h / 23 °C

16: CH₃SO₃H, 3 Angstroem molecular sieves / CH₂Cl₂ / 5 h / 23 °C

17: 72 percent / Et₃N, DMAP / CH₂Cl₂ / 6 h / 23 °C

18: 89 percent / DMAP / CH₂Cl₂ / 13 h / 23 °C

19: 92 percent / i-Pr₂NEt / CH₂Cl₂ / 0.33 h / 23 °C

20: 1.) Bu₃SnH, PdCl₂(PPh₃)2, HOAc, 2.) NaBH₃CN, HOAc / 1.) CH₂Cl₂, 23 deg C, 15 min, 2.) CH₃CN, 23 deg C, 30 min

With piperidine; dmap; bis-triphenylphosphine-palladium(II) chloride; potassium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; formic acid; methanesulfonic acid; Rh<(COD)-(R,R)-DIPAMP>(+)*BF4(-); 3 A molecular sieve; 4 A molecular sieve; diphenyl phosphoryl azide; boron trifluoride diethyl etherate; water; hydrogen; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; sodium cyanoborohydride; caesium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ja962480t

Reference yield:

: 187040-04-6
3-methyl-4,5-methylenedioxy salicylaldehyde

: 203922-35-4
C₄₄H₄₈F₃N₃O₁₀SSi

Guidance literature:: Multi-step reaction with 18 steps

1: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) DMF, 23 deg C, 40 min

2: 99 percent / piperidine, acetic acid / benzene / 18 h / 23 °C

3: 94 percent / Et₃N, HCOOH, Pd(PPh₃)4 / 4 h / 23 °C

4: (PhO)2P(O)N₃, Et₃N, 4 Angstroem molecular sieves / toluene / 2 h / 70 °C

5: 1 h / 23 °C

6: 97 percent / H₂, Rh<(COD)-(R,R)-DIPAMP>(+)*BF₄(-) / 16 h / 23 °C / 2280 Torr

7: BF₃*Et₂O, H₂O / CH₂Cl₂ / 0.17 h / 0 °C

8: BF₃*Et₂O, 4 Angstroem molecular sieves / CH₂Cl₂ / 18 h / 23 °C

9: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 6 h / 23 °C / 760 Torr

10: 61 percent / HOAc / 18 h / 23 °C

11: 87 percent / Cs₂CO₃ / dimethylformamide / 1 h / 23 °C

12: diisobutylaluminum hydride / toluene / 5 h / -78 °C

13: KF*2H₂O / methanol / 0.33 h / 23 °C

14: CH₃SO₃H, 3 Angstroem molecular sieves / CH₂Cl₂ / 5 h / 23 °C

15: 72 percent / Et₃N, DMAP / CH₂Cl₂ / 6 h / 23 °C

16: 89 percent / DMAP / CH₂Cl₂ / 13 h / 23 °C

17: 92 percent / i-Pr₂NEt / CH₂Cl₂ / 0.33 h / 23 °C

18: 1.) Bu₃SnH, PdCl₂(PPh₃)2, HOAc, 2.) NaBH₃CN, HOAc / 1.) CH₂Cl₂, 23 deg C, 15 min, 2.) CH₃CN, 23 deg C, 30 min

With piperidine; dmap; bis-triphenylphosphine-palladium(II) chloride; potassium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; methanesulfonic acid; Rh<(COD)-(R,R)-DIPAMP>(+)*BF4(-); 3 A molecular sieve; 4 A molecular sieve; diphenyl phosphoryl azide; boron trifluoride diethyl etherate; water; hydrogen; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; sodium cyanoborohydride; caesium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ja962480t