(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

Base Information

Chemical Name:(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene
CAS No.:131161-69-8
Molecular Formula:C₁₂H₁₄O
Molecular Weight:174.243
Hs Code.:

Synonyms:(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

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Chemical Property of (E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

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Technology Process of (E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

There total 7 articles about (E)-1-(2-cyclopropylvinyl)-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 6746-94-7
Cyclopropylacetylene

: 696-62-8
para-iodoanisole

: 131161-69-8
(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

Guidance literature:: Cyclopropylacetylene; With Schwartz's reagent; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; at 30 ℃; for 1h; Inert atmosphere;

para-iodoanisole; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; at 60 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2011.04.002

Reference yield: 61.0%

: 6303-59-9,60592-52-1,27570-08-7
(E)-4-(2-bromo-vinyl)-anisole

: 23719-80-4
cyclopropylmagnesium bromide

: 131161-69-8
(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

Guidance literature:: With C₃₂H₅₆Li₂NiO₄; In tetrahydrofuran; tert-butyl methyl ether; at -50 ℃; for 24h; Inert atmosphere;
DOI:10.1021/jacs.8b09849

Reference yield:

: 104-92-7
1-bromo-4-methoxy-benzene

: 1093195-43-7
(E)-(2-iodovinyl)cyclopropane

: 131161-69-8
(E)-1-(2-cyclopropylvinyl)-4-methoxybenzene

Guidance literature:: 1-bromo-4-methoxy-benzene; With tert.-butyl lithium; In tetrahydrofuran; at -78 - 23 ℃; for 0.666667h; Schlenk technique; Inert atmosphere;

(E)-(2-iodovinyl)cyclopropane; With iron(II) diacetylacetonate; XPhos; In toluene; at 0 - 23 ℃; for 8h; stereospecific reaction; Glovebox; Inert atmosphere;
DOI:10.1021/acs.orglett.1c01318