1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl

Base Information

• Chemical Name: 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl
• CAS No.: 763138-80-3
• Molecular Formula: C₃₀H₂₆N₂O₄S₂
• Molecular Weight: 542.679
• Mol file: 763138-80-3.mol

Synonyms:1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl

Chemical Property of 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl

There total 1 articles about 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(p-toluenesulfonyl)-1H-indole (31271-90-6) → 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,4']biindolyl + 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,5']biindolyl + 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,6']biindolyl + 1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl (763138-80-3)

Guidance literature:

With aluminium trichloride; In dichloromethane; at 25 ℃; for 0.0333333h; Further byproducts given;

DOI:10.1271/bbb.68.764

Reference yield: 91.0%

1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl (763138-80-3) → 1,1'-bis-(toluene-4-sulfonyl)-1H,1'H-[3,3']biindolyl (763138-83-6)

Guidance literature:

With manganese(IV) oxide; In 1,1,2,2-tetrachloroethane; at 100 ℃; for 1.5h;

DOI:10.1271/bbb.68.764

Reference yield:

1,1'-bis-(toluene-4-sulfonyl)-2,3-dihydro-1H,1'H-[3,3']biindolyl (763138-80-3) → 1H,1'H-[3,3']biindolyl (13637-37-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / MnO₂ / 1,1,2,2-tetrachloro-ethane / 1.5 h / 100 °C

2: 57 percent / KOH / dioxane / 0.83 h / 100 °C

With manganese(IV) oxide; potassium hydroxide; In 1,4-dioxane; 1,1,2,2-tetrachloroethane;

DOI:10.1271/bbb.68.764

upstream raw materials:

1-(p-toluenesulfonyl)-1H-indole

Downstream raw materials:

1,1'-bis-(toluene-4-sulfonyl)-1H,1'H-[3,3']biindolyl

1H,1'H-[3,3']biindolyl