2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

Base Information

Chemical Name:2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester
CAS No.:1384950-10-0
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:

Synonyms:2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

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Chemical Property of 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

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Technology Process of 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

There total 1 articles about 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77869-48-8
4,7-dimethyl-8-methoxycoumarin

: 1384950-10-0
2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: potassium hydroxide / water; ethylene glycol / 2 h / Reflux; Inert atmosphere

2: potassium carbonate; potassium iodide / acetone / 5 h / Reflux; Inert atmosphere

With potassium carbonate; potassium iodide; potassium hydroxide; In water; ethylene glycol; acetone;
DOI:10.1016/j.tet.2012.05.041

Reference yield: 90.0%

: 1384950-10-0
2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

: 74-88-4
methyl iodide

: 1384950-13-3
2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-2-methyl-propionic acid methyl ester

Guidance literature:: 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -40 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; hexane; at -40 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2012.05.041

Reference yield:

: 1384950-10-0
2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester

: 123085-55-2
1-(1,5-dimethylhex-4-en-1-yl)-2,3-dimethoxy-4-methylbenzene

Guidance literature:: Multi-step reaction with 9 steps

1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 0.5 h / -40 °C / Inert atmosphere

1.2: -40 - 20 °C / Inert atmosphere

2.1: sodium hydroxide / methanol; water / 1 h / 50 °C

2.2: Cooling

3.1: thionyl chloride / benzene / 3 h / Reflux; Inert atmosphere

4.1: palladium diacetate / diethyl ether / 3 h / 0 - 20 °C / Inert atmosphere

5.1: palladium 10% on activated carbon; hydrogen / ethanol / 2 h / 20 °C / 760.05 Torr

6.1: sodium tetrahydroborate / methanol / 2 h / 0 °C

6.2: Cooling

7.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C / Inert atmosphere

7.2: 8 h / 20 °C / Inert atmosphere

8.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / Inert atmosphere; Reflux

9.1: potassium carbonate; potassium iodide / acetone / Reflux; Inert atmosphere

With sodium tetrahydroborate; n-butyllithium; thionyl chloride; 2,2'-azobis(isobutyronitrile); palladium 10% on activated carbon; hydrogen; tri-n-butyl-tin hydride; palladium diacetate; sodium hydride; potassium carbonate; diisopropylamine; potassium iodide; sodium hydroxide; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; water; acetone; toluene; mineral oil; benzene;
DOI:10.1016/j.tet.2012.05.041