phenylthio-4-pentenol

Base Information

• Chemical Name: phenylthio-4-pentenol
• CAS No.: 111341-49-2
• Molecular Formula: C₁₁H₁₄OS
• Molecular Weight: 194.298
• Mol file: 111341-49-2.mol

Synonyms:phenylthio-4-pentenol

Chemical Property of phenylthio-4-pentenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of phenylthio-4-pentenol

There total 1 articles about phenylthio-4-pentenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-Pent-4-enyl alcohol (821-09-0) + benzenesulfenyl chloride (931-59-9) → phenylthio-4-pentenol (111341-49-2)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) hexane, ether, 21 deg C; 2.) hexane, ether, 21 deg C, 2 h;

Reference yield: 50.0%

phenylthio-4-pentenol (111341-49-2) → n-Pent-4-enyl alcohol (821-09-0) + 2-<(phenylthio)methyl>tetrahydrofuran (17414-08-3)

Guidance literature:

With silica gel; In diethyl ether; at 21 ℃;

Reference yield: 26.0%

phenylthio-4-pentenol (111341-49-2) → 2-methyltetrahydrofuran (96-47-9) + n-Pent-4-enyl alcohol (821-09-0)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In various solvent(s); at 80 ℃; for 0.5h; Rate constant; Mechanism; Bu₃Sn^. effect in S_H2 displacement of alkoxy radicals from sulphur, exo cyclization;

DOI:10.1039/c39890001202

upstream raw materials:

n-Pent-4-enyl alcohol

benzenesulfenyl chloride

Downstream raw materials:

2-methyltetrahydrofuran

n-Pent-4-enyl alcohol

2-<(phenylthio)methyl>tetrahydrofuran

(E)-5-(phenylthio)pent-4-en-1-ol

Refernces