2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

Base Information

Chemical Name:2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate
CAS No.:188472-63-1
Molecular Formula:C₁₈H₃₀O₇Si
Molecular Weight:386.518
Hs Code.:

Synonyms:2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

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Chemical Property of 2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

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Technology Process of 2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

There total 7 articles about 2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 129245-42-7
2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-4-methoxy-5-methyl-2-(2-trimethylsilyl-3-furyl)cyclohexanecarboxylate

: 188472-63-1
2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

Guidance literature:: With oxygen; 5,15,10,20-tetraphenylporphyrin; In methanol; dichloromethane; at -78 ℃; for 0.333333h; Irradiation;
DOI:10.1039/a605894i

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 188472-63-1
2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / DMAP, DCC / CH₂Cl₂ / 16 h / Ambient temperature

2: 91 percent / O₂, tetraphenylporphyrin / CH₂Cl₂; methanol / 0.33 h / -78 °C / Irradiation

With dmap; oxygen; 5,15,10,20-tetraphenylporphyrin; dicyclohexyl-carbodiimide; In methanol; dichloromethane;
DOI:10.1039/a605894i

Reference yield:

: 129245-41-6
(1R,2S,4S,5S)-2-Hydroxy-4-methoxy-5-methyl-2-(2-trimethylsilyl-3-furyl)cyclohexanecarboxylic acid

: 188472-63-1
2-Trimethylsilylethyl (1R,2S,4S,5S)-2-hydroxy-2-(5-hydroxy-2-oxo-1-oxacyclopent-3-en-3-yl)-4-methoxy-5-methylcyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / DMAP, DCC / CH₂Cl₂ / 16 h / Ambient temperature

2: 91 percent / O₂, tetraphenylporphyrin / CH₂Cl₂; methanol / 0.33 h / -78 °C / Irradiation

With dmap; oxygen; 5,15,10,20-tetraphenylporphyrin; dicyclohexyl-carbodiimide; In methanol; dichloromethane;
DOI:10.1039/a605894i