rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

Base Information

Chemical Name:rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene
CAS No.:1569019-04-0
Molecular Formula:C₁₈H₂₀O₂
Molecular Weight:268.356
Hs Code.:

Synonyms:rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

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Technology Process of rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

There total 3 articles about rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 88738-40-3,91970-13-7
γ-Phenyl-allylalkohol-methoxy-methylether

: 908094-04-2
phenyldiazomethane

: 1569019-04-0
rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

Guidance literature:: With zinc(II) iodide; In dichloromethane; at 20 ℃; for 0.25h;
DOI:10.1002/anie.201608444

Reference yield:

: 100-52-7
benzaldehyde

: 1569019-04-0
rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: methanol / 20 °C / Inert atmosphere

1.2: 0.25 h / 0 - 20 °C / Inert atmosphere

2.1: neat (no solvent) / 100 - 200 °C / Inert atmosphere

3.1: diethylzinc; iodine / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

With iodine; diethylzinc; In methanol; dichloromethane; 3.1: |Simmons-Smith Cyclopropanation;
DOI:10.1021/ol500267w

Reference yield:

: 16182-18-6
benzaldehyde 2,4,6-trimethylbenzenesulfonyl hydrazone

: 1569019-04-0
rel-((1R,2S,3R)-3-((methoxymethoxy)methyl)cyclopropane-1,2-diyl)dibenzene

Guidance literature:: Multi-step reaction with 2 steps

1: N,N,N',N'-tetramethylguanidine / dichloromethane; formamide / 65 °C / Flow reactor

2: zinc(II) iodide / dichloromethane / 0.25 h / 20 °C

With zinc(II) iodide; N,N,N',N'-tetramethylguanidine; In dichloromethane; formamide;
DOI:10.1002/anie.201608444