(3-Chloropropyl)diphenylsulfonium Tetrafluoroborate

Base Information

• Chemical Name: (3-Chloropropyl)diphenylsulfonium Tetrafluoroborate
• CAS No.: 33462-80-5
• Molecular Formula: C15H16BClF4S
• Molecular Weight: 350.616
• Hs Code.: 2930909090
• European Community (EC) Number: 630-894-3
• DSSTox Substance ID: DTXSID20371507
• Mol file: 33462-80-5.mol

Synonyms:(3-Chloropropyl)diphenylsulfonium Tetrafluoroborate;33462-80-5;3-chloropropyl(diphenyl)sulfanium;tetrafluoroborate;(3-CHLOROPROPYL)DIPHENYLSULFONIUMTETRAFLUOROBORATE;SCHEMBL11339265;DTXSID20371507;MFCD00074932;AKOS015832959;AS-81153;CS-0362917;FT-0604705;T70787;(3-Chloropropyl)diphenylsulphoniumtetrafluoroborate;3-Chloropropyl(diphenyl)sulfonium tetrafluoroborate;J-019197;(3-chloropropyl)diphenylsulfanium;tetrafluoroboranuide;(3-Chloropropyl)(diphenyl)sulfonium tetrafluoroborate, AldrichCPR

Chemical Property of (3-Chloropropyl)diphenylsulfonium Tetrafluoroborate

Chemical Property:

• Melting Point: 107.0 to 111.0 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 25.30000
• Density: g/cm³
• LogP: 5.65180
• Solubility.: soluble in Acetone
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 5
• Exact Mass: 350.0690422
• Heavy Atom Count: 22
• Complexity: 196

Purity/Quality:

98%,99%, ^*data from raw suppliers

(3-Chloropropyl)diphenylsulfonium Tetrafluoroborate >98.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.C1=CC=C(C=C1)[S+](CCCCl)C2=CC=CC=C2

Technology Process of (3-Chloropropyl)diphenylsulfonium Tetrafluoroborate

There total 6 articles about (3-Chloropropyl)diphenylsulfonium Tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

diphenyl sulfide (139-66-2) → (3-chloropropyl)diphenylsulfonium tetrafluoroborate (33462-80-5)

Guidance literature:

With silver tetrafluoroborate; at 20 ℃; for 72h;

DOI:10.1021/jo991549n

Reference yield:

1-iodo-3-chloro-propane (6940-76-7) + diphenyl sulfide (139-66-2) → (3-chloropropyl)diphenylsulfonium tetrafluoroborate (33462-80-5)

Guidance literature:

With silver tetrafluoroborate; In nitromethane;

DOI:10.1021/ja00797a034

Reference yield:

silver tetrafluoroborate (14104-20-2) + 1-iodo-3-chloro-propane (6940-76-7) + diphenyl sulfide (139-66-2) → (3-chloropropyl)diphenylsulfonium tetrafluoroborate (33462-80-5)

Guidance literature:

In nitromethane; at 20 ℃; for 20h; Inert atmosphere;

upstream raw materials:

1-iodo-3-chloro-propane

diphenyl sulfide

3-chloropropyl phenyl ether

1-chloro-3-hydroxypropane

Downstream raw materials:

cyclopropyldiphenylsulfonium tetrafluoroborate

Refernces

• 1、 -. "CYCLIC COMPOUNDS AS IMMUNOMODULATING AGENTS". Page/Page column 35; 64; 65. . Retrieved 2019/05/10.
• 2、 Matsuyama, Haruo,Nakamura, Takako,Iyoda, Masahiko. "Synthesis of Fischer-Type (Alkoxy)carbene Complexes Using Diphenylsulfonium Salts with Functionalized Alkyl Groups". . p. 4796 - 4803. Retrieved 2007/10/03.