[(C₆Me₆)H][Al(OC(CF₃)3)4]

Base Information

• Chemical Name: [(C₆Me₆)H][Al(OC(CF₃)3)4]
• CAS No.: 874445-84-8
• Molecular Formula: C₁₂H₁₈*C₁₆AlF₃₆O₄*H
• Molecular Weight: 1130.38
• Mol file: 874445-84-8.mol

Synonyms:[(C₆Me₆)H][Al(OC(CF₃)3)4]

Chemical Property of [(C₆Me₆)H][Al(OC(CF₃)3)4]

Chemical Property:

Purity/Quality:

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Technology Process of [(C₆Me₆)H][Al(OC(CF₃)3)4]

There total 2 articles about [(C₆Me₆)H][Al(OC(CF₃)3)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

Li[Al(perfluoro-tertbutoxide)4] + Bi5(3+)*3AsF6(1-)*SO2=[Bi5](AsF6)3*SO2 + Hexamethylbenzene (87-85-4) → bismuth (7440-69-9) + [(C6Me6)H][Al(OC(CF3)3)4] (874445-84-8) + [Bi5(hexamethylbenzene)4][Al(OC(CF3)3)4]3 + [Bi4OF2Cl6(hexamethylbenzene)4][Al(OC(CF3)3)4]2*hexamethylbenzene

Guidance literature:

In dichloromethane; byproducts: LiAsF6; under N2, 1 equiv. of Li-compd., 1 equiv. of Bi-compd. and 2 equiv. of C6Me6 were stirred in CH2Cl2 for 4 h, 5 °C; soln. was concd., held at -24 °C for 2 d, crystals were sepd., another crop was given after 2 d at this temp., elem. anal.; keeping the mother liq. for 2 weeks, Bi, the Bi4OF2Cl6(2+) and C6Me6H(1+)-cation con tg. compds. were formed.;

DOI:10.1016/j.poly.2005.06.032

Reference yield:

Li[Al(perfluoro-tertbutoxide)4] + Bi5(3+)*3AsF6(1-)*SO2=[Bi5](AsF6)3*SO2 + Hexamethylbenzene (87-85-4) → bismuth (7440-69-9) + [(C6Me6)H][Al(OC(CF3)3)4] (874445-84-8) + [Bi4OF2Cl6(hexamethylbenzene)4][Al(OC(CF3)3)4]2*hexamethylbenzene

Guidance literature:

In dichloromethane; under N2, 3 equiv. of Li-compd., 1 equiv. of Bi-compd. and 5 equiv. of C6Me6 were stirred in CH2Cl2 for 4 h; soln. was concd., held at -24 °C for 2 weeks. soln. was filtered,concd., held at -24 °C for 3 weeks, crystals were sepd. by manua lly, Bi-contg. and not-Bi-contg. products ratio was. 3:1, elem. anal.;

DOI:10.1016/j.poly.2005.06.032

upstream raw materials:

Hexamethylbenzene