(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

Base Information

Chemical Name:(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol
CAS No.:152984-40-2
Molecular Formula:C₂₆H₃₆O₅
Molecular Weight:428.569
Hs Code.:

Synonyms:(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

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Chemical Property of (1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

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Technology Process of (1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

There total 6 articles about (1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 131934-36-6
1-bromo-3-(methoxymethoxy)cyclohexene

: 152984-34-4
(1S,4R)-1-<(E)-2-(p-Methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanone

: 152984-40-2
(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

Guidance literature:: With cerium(III) chloride; tert.-butyl lithium; vinyllithium; In tetrahydrofuran; pentane; 1.) -78 deg C, 50 min, 2.) -78 deg C, 1 h;
DOI:10.1021/jo00076a058

Reference yield:

: 35657-08-0
p-methoxyphenoxymethyl chloride

: 152984-40-2
(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

Guidance literature:: Multi-step reaction with 3 steps

1: benzene / 24 h / Heating

2: 52 percent / n-BuLi / tetrahydrofuran; hexane / 1.) -78 deg C, 10 min, 2.) -78 deg C -> r.t.

3: 77 percent / CeCl₃, t-BuLi, vinyllithium / tetrahydrofuran; pentane / 1.) -78 deg C, 50 min, 2.) -78 deg C, 1 h

With n-butyllithium; cerium(III) chloride; tert.-butyl lithium; vinyllithium; In tetrahydrofuran; hexane; pentane; benzene;
DOI:10.1021/jo00076a058

Reference yield:

: 86023-73-6,6004-71-3
7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carbaldehyde

: 152984-40-2
(1S,2S,4R)-2-<(R)-3-(Methoxymethoxy)-1-cyclohexen-1-yl>-1-<(E)-2-(p-methoxyphenoxy)vinyl>-7,7-dimethyl-2-norbornanol

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / n-BuLi / tetrahydrofuran; hexane / 1.) -78 deg C, 10 min, 2.) -78 deg C -> r.t.

2: 77 percent / CeCl₃, t-BuLi, vinyllithium / tetrahydrofuran; pentane / 1.) -78 deg C, 50 min, 2.) -78 deg C, 1 h

With n-butyllithium; cerium(III) chloride; tert.-butyl lithium; vinyllithium; In tetrahydrofuran; hexane; pentane;
DOI:10.1021/jo00076a058