di(ferrocenylethynyl)phenylphosphane

Base Information

Chemical Name:di(ferrocenylethynyl)phenylphosphane
CAS No.:916074-57-2
Molecular Formula:C₃₀H₂₃Fe₂P
Molecular Weight:526.18
Hs Code.:

Synonyms:di(ferrocenylethynyl)phenylphosphane

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Chemical Property of di(ferrocenylethynyl)phenylphosphane

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Technology Process of di(ferrocenylethynyl)phenylphosphane

There total 1 articles about di(ferrocenylethynyl)phenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1271-47-2
ferroceneacetylene

: 644-97-3
Dichlorophenylphosphine

: 916074-57-2
di(ferrocenylethynyl)phenylphosphane

Guidance literature:: With n-butyl lithium; In tetrahydrofuran; byproducts: LiCl; under Ar, Schlenk techniques; n-BuLi/hexane added dropwise to soln. of Fe complex in THF at -78°C, warmed to room temp., kept for 30 min,PhPCl2 added dropwise at -78°C, warmed, kept at room temp. for 2 h; evapd. under vac., residue dissolved in CH2Cl2, soln. filtered, filtrateconcd., filtered over alumina using pentane as eluent, filtrate evapd.; elem. anal.;
DOI:10.1021/om0606892

Reference yield: 93.0%

: 7782-49-2
selenium

: 916074-57-2
di(ferrocenylethynyl)phenylphosphane

: 1100746-34-6
di(ferrocenylethynyl)phenylphosphane selenide

Guidance literature:: In toluene; under N2; Fe-contg. compd. (0.30 mmol) was dissolved in toluene and Se (0.57 mmol) was added; stirring at 100°C for 12 h; volatiles were removed under vac.; the residue was dissolved in CH2Cl2 and filtered through a pad of Celite; the soln. was concd.; addn. of petroleum ether; elem. anal.;
DOI:10.1016/j.jorganchem.2008.09.040

Reference yield: 92.0%

: 14873-63-3,15617-19-3,51921-56-3
bis(benzonitrile)dichloroplatinum(II)

: 916074-57-2
di(ferrocenylethynyl)phenylphosphane

: cis-[((ferrocene-ethynyl)2PhP)2PtCl₂]

Guidance literature:: In dichloromethane; byproducts: C6H5CN; (N2); using Schlenk techniques; dissolving of (PhCN)2PtCl2 and (ferrocene-ethynyl)2PhP (2 equiv.) in CH2Cl2; stirring for 1 h at 25°C; concn. under reduced pressure; pptn. by addn. of petroleum ether; elem. anal.;
DOI:10.1016/j.jorganchem.2008.11.046