(S)-1-(2-methylphenyl)-prop-2-en-1-amine

Base Information

Chemical Name:(S)-1-(2-methylphenyl)-prop-2-en-1-amine
CAS No.:688362-65-4
Molecular Formula:C₁₀H₁₃N
Molecular Weight:147.22
Hs Code.:

Synonyms:(S)-1-(2-methylphenyl)-prop-2-en-1-amine

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Chemical Property of (S)-1-(2-methylphenyl)-prop-2-en-1-amine

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Technology Process of (S)-1-(2-methylphenyl)-prop-2-en-1-amine

There total 7 articles about (S)-1-(2-methylphenyl)-prop-2-en-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3938-96-3
ethyl 2-methoxyacetate

: (+/-)-1-(2-methylphenyl)-2-propenylamine

: 1213047-60-9
(R)-1-(2-methylphenyl)-prop-2-en-1-amine

: 688362-65-4
(S)-1-(2-methylphenyl)-prop-2-en-1-amine

: C₁₃H₁₇NO₂

Guidance literature:: With immobilized lipase B from Candida antarctica; In tert-butyl methyl ether; at 30 ℃; for 192h; optical yield given as %ee; enantioselective reaction; Enzymatic reaction;
DOI:10.1016/j.tetasy.2011.06.004

Reference yield:

: 3938-96-3
ethyl 2-methoxyacetate

: 1332887-98-5
2,2,2-trichloro-N-[1-(2-methylphenyl)allyl]acetamide

: 1213047-60-9
(R)-1-(2-methylphenyl)-prop-2-en-1-amine

: 688362-65-4
(S)-1-(2-methylphenyl)-prop-2-en-1-amine

: 688362-51-8
(+/-)-N-1-acetyl-1-(2-methylphenyl)-2-propenylamine

Guidance literature:: 2,2,2-trichloro-N-[1-(2-methylphenyl)allyl]acetamide; With sodium hydroxide; In ethanol; Inert atmosphere;

ethyl 2-methoxyacetate; With Candida antarctica lipase B immobilized on acrylic resin; In tert-butyl methyl ether; at 30 ℃; for 192h; enantioselective reaction; Inert atmosphere; Resolution of racemate; Enzymatic reaction;
DOI:10.1002/ejoc.201800346

Reference yield:

: 24393-48-4
ethyl trans-2-methylcinnamate

: 1213047-60-9
(R)-1-(2-methylphenyl)-prop-2-en-1-amine

: 688362-65-4
(S)-1-(2-methylphenyl)-prop-2-en-1-amine

: C₁₃H₁₇NO₂

Guidance literature:: Multi-step reaction with 5 steps

1: diisobutylaluminium hydride / dichloromethane; toluene / 3 h / -30 °C / Inert atmosphere

2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.25 h / 0 °C

3: potassium carbonate / 5,5-dimethyl-1,3-cyclohexadiene / 24 h / 140 °C

4: sodium hydroxide / ethanol; water / 24 h / 20 °C

5: immobilized lipase B from Candida antarctica / tert-butyl methyl ether / 192 h / 30 °C / Enzymatic reaction

With immobilized lipase B from Candida antarctica; diisobutylaluminium hydride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium hydroxide; In 5,5-dimethyl-1,3-cyclohexadiene; ethanol; dichloromethane; tert-butyl methyl ether; water; toluene;
DOI:10.1016/j.tetasy.2011.06.004