(6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol

Base Information

• Chemical Name: (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol
• CAS No.: 127229-92-9
• Molecular Formula: C₃₄H₂₈N₂O₂
• Molecular Weight: 496.609

Synonyms:(6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol

Chemical Property of (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol

There total 7 articles about (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

cis-5,6a,11,12a-Tetrahydro-5,11-dimethylpentaleno<2,1-b:5,4-b'>diindole-6,12-dione (127229-87-2) + phenyllithium (591-51-5) → (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol (127229-92-9)

Guidance literature:

In tetrahydrofuran; for 48h; Ambient temperature;

DOI:10.1021/jo00299a031

Reference yield:

cis-bicyclo[3. 3. 0]octane-3,7-dione (51716-63-3) → (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol (127229-92-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 50 percent

2: 56 percent / SeO₂ / dioxane / 48 h / Heating

3: 96 percent / tetrahydrofuran / -78 to 25 deg C

With selenium(IV) oxide; In tetrahydrofuran; 1,4-dioxane;

DOI:10.1016/S0040-4020(01)80896-6

Reference yield:

phenylhydrazine (100-63-0) → (6α,6aβ,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-diphenylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol (127229-92-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 20 percent / HCl / ethanol / Δ

2: 90 percent / NaH / tetrahydrofuran

3: 56 percent / SeO₂ / dioxane / 48 h / Heating

4: 96 percent / tetrahydrofuran / -78 to 25 deg C

With selenium(IV) oxide; sodium hydride; hydrogenchloride; In tetrahydrofuran; 1,4-dioxane; ethanol;

DOI:10.1016/S0040-4020(01)80896-6

upstream raw materials:

cis-5,6a,11,12a-Tetrahydro-5,11-dimethylpentaleno<2,1-b:5,4-b'>diindole-6,12-dione

phenyllithium

cis-bicyclo[3. 3. 0]octane-3,7-dione

cis-5,6,6a,11,12,12a-Hexahydro-5,11-dihydropentaleno<2,1-b:5,4-b'>diindole

Downstream raw materials:

<3-(1,4-Dihydro-4-methyl-2-phenylcyclopentindol-1-yl)-1-methyl-1H-indol-2-yl>phenylmethanone

<1-Methyl-3-(1,2,3,4-tetrahydro-4-methyl-3-phenyl-1-(phenylseleno)cyclopentindol-2-yl)-1H-indol-2-yl>phenylmethanone

4-Methyl-1-[1-(1-methyl-1H-indol-2-yl)-1-phenyl-meth-(E)-ylidene]-3-phenyl-1,4-dihydro-cyclopenta[b]indole

C₃₄H₂₆N₂O

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