(4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))

Base Information

• Chemical Name: (4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))
• CAS No.: 1137765-77-5
• Molecular Formula: C₃₅H₃₁BO₃
• Molecular Weight: 510.44
• Mol file: 1137765-77-5.mol

Synonyms:(4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))

Chemical Property of (4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))

There total 5 articles about (4-MeOC₄H₄CH₂CH₂)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

4-Methoxystyrene (637-69-4,24936-44-5) + 4,4,5,5-tetraphenyl-1,3,2-dioxaborolane (532402-37-2) → (4-MeOC4H4CH2CH2)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H)) (1137765-77-5)

Guidance literature:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; In toluene; for 18h;

DOI:10.1002/ejic.200701066

Reference yield: 20.0%

4-Methoxystyrene (637-69-4,24936-44-5) + 4,4,5,5-tetraphenyl-1,3,2-dioxaborolane (532402-37-2) → (4-MeOC4H4CH(Me))(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H)) (1137765-74-2) + (4-MeOC4H4CH2CH2)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H)) (1137765-77-5) + (4-MeOC4H4CHCH)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H))

Guidance literature:

Rh(acac)(dppb); In benzene-d6; byproducts: CH3OC6H4CH2CH3; B compd. (0.13 mmol) and ligand (0.13 mmol) in the presence of Rh compd.(0.0015 mmol) stored for 18 h; NMR;

DOI:10.1002/ejic.200701066

Reference yield:

tetraphenylethane-1,2-diol (464-72-2) → (4-MeOC4H4CH2CH2)(4,4,5,5-tetraphenyl-1,3,2-dioxoborolane(-H)) (1137765-77-5)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] / toluene

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; In toluene;

DOI:10.1002/ejic.200701066

upstream raw materials:

4-Methoxystyrene

4,4,5,5-tetraphenyl-1,3,2-dioxaborolane

tetraphenylethane-1,2-diol