(+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane

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Chemical Name:(+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane
CAS No.:80145-77-3
Molecular Formula:0CH₂Cl₂*C₂₈H₃₂Cl₂N₂Pd₂
Molecular Weight:722.788
Hs Code.:

Synonyms:(+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane

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Chemical Property of (+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane

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Technology Process of (+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane

There total 1 articles about (+)589-bis(μ-chloro)bis{(R)-{1-(dimethylamino)ethyl}naphthalenyl-C2,N}dipalladium(II) - 0.5-dichloromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: lithium tetrachloropalladate(II)

: 119392-95-9,121045-73-6
(R_c)-1-(1'-N,N-dimethylaminoethyl)naphthalene

: 80145-77-3
bis(μ-chloro)bis[(R)-2-[1-(dimethylamino)ethyl]-naphthyl-C,N]dipalladium(II)

Guidance literature:: With (C₂H₅)3N; In methanol; treating Pd-complex with 1 equiv. each of naphthalene-derivative and Et3N in MeOH;

Reference yield: 96.0%

: 80145-77-3
bis(μ-chloro){bis{(R)-1-(dimethylamino)ethyl}naphthylenyl-C2,N}-dipalladium(II) dichloromethane

: 20859-51-2
1-(methylthio)-2-(diphenylphosphino)ethane

: {(R)-1-{1-(dimethylamino)ethyl}-2-naphtalenyl-C₂,N}{(2-(methylthio)-ethyl)diphenylphosphine-P,S} palladium (II) chloride

Guidance literature:: In dichloromethane; (N2), stirred until soln. homogeneous; glass;

Reference yield: 90.0%

: ammonium hexafluorophosphate

: 80145-77-3
bis(μ-chloro)bis[(R)-2-[1-(dimethylamino)ethyl]-naphthyl-C,N]dipalladium(II)

: 90971-53-2,91049-53-5,91049-58-0
(2-Aminoethyl)methylphenylarsine

: [SP-4-2-(R,R)]-[1-amino-2-(methylphenylarsino)ethane-As,N][1-[1-(dimethylamino)ethyl]-naphthyl-C,N]palladium(II) hexafluorophosphate acetone solvate

: 90971-56-5
[SP-4-2-(R,S)]-[1-amino-2-(methylphenylarsino)ethane-As,N][1-[1-(dimethylamino)ethyl]-naphthyl-C,N]palladium(II) hexafluorophosphate

Guidance literature:: In methanol; water; adding soln. of arsine to methanolic suspn. of Pd-complex; stirring for1h at 25°C; treating with NH4PF6 in H2O, after 30 min formation of a white ppt.; filtration; washing residue (H2O), dissolving in CH2Cl2; drying; evapn.yielded a mixture of R,R- and R,S-diastereoisomers; dissolving in hot acetone; slow cooling; standing at 5°C for 16h; concg. yielded thesolvate; elem. anal.;