1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

Base Information

Chemical Name:1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene
CAS No.:869338-52-3
Molecular Formula:C₂₈H₅₂O₄Si₂
Molecular Weight:508.889
Hs Code.:

1-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-4-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

Synonyms:1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

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Chemical Property of 1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

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Technology Process of 1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

There total 5 articles about 1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: (2R,3S,4S)-5-(4-Methoxy-benzyloxy)-4-methyl-2-vinyl-pentane-1,3-diol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 869338-52-3
1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

Guidance literature:: DOI:10.1021/ol051691c

Reference yield:

: 869338-51-2
(E)-(R)-5-(4-Methoxy-benzyloxy)-4-methyl-pent-2-enoic acid methyl ester

: 869338-52-3
1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / DIBAL / CH₂Cl₂; toluene / 2 h / -78 °C

2: 90 percent / 3 Angstroem molecular sieves; diethyl (+)-tartrate; t-BuOOH / Ti(O-iPr)4 / CH₂Cl₂; decane / 20 h / -30 °C

3: 67 percent / CuI

With tert.-butylhydroperoxide; copper(l) iodide; diethyl (2R,3R)-tartrate; 3 A molecular sieve; diisobutylaluminium hydride; titanium(IV) isopropylate; In decane; dichloromethane; toluene;
DOI:10.1021/ol051691c

Reference yield:

: 132969-60-9
(2S)-3-[(4-methoxybenzyl)oxy]-2-methylpropanal

: 869338-52-3
1-[3-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-hex-5-enyloxymethyl]-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / benzene / 20 h / 20 °C

2: 95 percent / DIBAL / CH₂Cl₂; toluene / 2 h / -78 °C

3: 90 percent / 3 Angstroem molecular sieves; diethyl (+)-tartrate; t-BuOOH / Ti(O-iPr)4 / CH₂Cl₂; decane / 20 h / -30 °C

4: 67 percent / CuI

With tert.-butylhydroperoxide; copper(l) iodide; diethyl (2R,3R)-tartrate; 3 A molecular sieve; diisobutylaluminium hydride; titanium(IV) isopropylate; In decane; dichloromethane; toluene; benzene;
DOI:10.1021/ol051691c