C₃₄H₅₄O₈Si

Base Information

Chemical Name:C₃₄H₅₄O₈Si
CAS No.:1313046-75-1
Molecular Formula:C₃₄H₅₄O₈Si
Molecular Weight:618.883
Hs Code.:

C<sub>34</sub>H<sub>54</sub>O<sub>8</sub>Si

Synonyms:C₃₄H₅₄O₈Si

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Chemical Property of C₃₄H₅₄O₈Si

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of C₃₄H₅₄O₈Si

There total 17 articles about C₃₄H₅₄O₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1313046-73-9
C₃₂H₅₂O₇Si

: 64-19-7,77671-22-8
acetic acid

: 1313046-75-1
C₃₄H₅₄O₈Si

Guidance literature:: With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine; In benzene; at 0 - 70 ℃; Inert atmosphere;
DOI:10.1021/ol201464m

Reference yield:

: 942133-13-3
(2R,3S,E)-((1R,2S)-2-(N-benzyl-2,4,6-trimethylphenylsulfonamido)-1-phenylpropyl) 3-hydroxy-5-iodo-2,4-dimethylpent-4-enoate

: 1313046-75-1
C₃₄H₅₄O₈Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: dmap; triethylamine / dichloromethane / 0 - 23 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.5 h / 0 °C / Inert atmosphere

3.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

4.1: water; barium(II) oxide / diethyl ether / 0 - 20 °C / Inert atmosphere

4.2: 48 h / 0 °C / Inert atmosphere

5.1: trimethyltin(IV) hydroxide / 1,2-dichloro-ethane / 12 h / 80 °C / Inert atmosphere

6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / water; acetonitrile / -5 - 0 °C / Inert atmosphere

7.1: dmap; 2-methyl-6-nitrobenzoic anhydride / dichloromethane / 12 h / 20 °C / Inert atmosphere

8.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 1 h / -40 °C / Inert atmosphere

9.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; [Ph₂PO-][NBu₄+] / N,N-dimethyl-formamide / 1.5 h / 20 °C / Inert atmosphere

10.1: tributylphosphine; 1,1'-azodicarbonyl-dipiperidine / benzene / 0 - 70 °C / Inert atmosphere

With dmap; sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; tributylphosphine; cerium(III) chloride heptahydrate; [Ph₂PO-][NBu₄+]; 2-methyl-6-nitrobenzoic anhydride; water; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; trimethyltin(IV) hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; barium(II) oxide; 1,1'-azodicarbonyl-dipiperidine; In methanol; diethyl ether; hexane; dichloromethane; water; 1,2-dichloro-ethane; N,N-dimethyl-formamide; acetonitrile; benzene; 4.1: Horner-Wadsworth-Emmons reaction / 4.2: Horner-Wadsworth-Emmons reaction / 8.1: Luche reduction / 9.1: Stille coupling / 10.1: Mitsunobu reaction;
DOI:10.1021/ol201464m

Reference yield:

: 1313046-59-1
(2S,3S,4E)-5-iodo-2,4-dimethyl-3-[(triethylsilyl)oxy]pent-4-en-1-ol

: 1313046-75-1
C₃₄H₅₄O₈Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

2.1: water; barium(II) oxide / diethyl ether / 0 - 20 °C / Inert atmosphere

2.2: 48 h / 0 °C / Inert atmosphere

3.1: trimethyltin(IV) hydroxide / 1,2-dichloro-ethane / 12 h / 80 °C / Inert atmosphere

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / water; acetonitrile / -5 - 0 °C / Inert atmosphere

5.1: dmap; 2-methyl-6-nitrobenzoic anhydride / dichloromethane / 12 h / 20 °C / Inert atmosphere

6.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 1 h / -40 °C / Inert atmosphere

7.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; [Ph₂PO-][NBu₄+] / N,N-dimethyl-formamide / 1.5 h / 20 °C / Inert atmosphere

8.1: tributylphosphine; 1,1'-azodicarbonyl-dipiperidine / benzene / 0 - 70 °C / Inert atmosphere

With dmap; sodium tetrahydroborate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; tributylphosphine; cerium(III) chloride heptahydrate; [Ph₂PO-][NBu₄+]; 2-methyl-6-nitrobenzoic anhydride; water; sodium hydrogencarbonate; Dess-Martin periodane; trimethyltin(IV) hydroxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; barium(II) oxide; 1,1'-azodicarbonyl-dipiperidine; In methanol; diethyl ether; dichloromethane; water; 1,2-dichloro-ethane; N,N-dimethyl-formamide; acetonitrile; benzene; 2.1: Horner-Wadsworth-Emmons reaction / 2.2: Horner-Wadsworth-Emmons reaction / 6.1: Luche reduction / 7.1: Stille coupling / 8.1: Mitsunobu reaction;
DOI:10.1021/ol201464m