(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Base Information

Chemical Name:(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)
CAS No.:1023596-51-1
Molecular Formula:C₄₉H₅₁N₅Zn
Molecular Weight:775.367
Hs Code.:

Synonyms:(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

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Chemical Property of (5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

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Technology Process of (5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

There total 1 articles about (5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 557-21-1
zinc(II) cyanide

: 5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrin

: 7440-66-6
zinc

: 1023596-51-1
(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:: With 1,1'-bis(diphenylphosphino)ferrocene; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In N,N-dimethyl acetamide; under N2 atm.; Pd complex, Fe complex, Zn, Zn(CN)2 and C48H52N4Br2 mixedwith anhyd. DMA, stirred overnight (12 h) at 120°C; sepd. with CH2Cl2, washed with 12 % aq. NH4OH, then with H2O; org. layerconcd. on rotary evaporator, sepd. by chromy. (silica gel, CH2Cl2/n-C6C 14); centrifuged, resuspended in n-C7H16, centrifuged, dried in vac.;
DOI:10.1021/jp801510b

Reference yield: 70.0%

: 128-08-5
N-Bromosuccinimide

: 1023596-51-1
(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

: 1023596-52-2
(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:: In pyridine; dichloromethane; under N2 or Ar atm.; Zn complex dissolved in CH2Cl2, cooled to 0°C, pyridine syringed, n-bromosuccinimide added, stirred for 30 min at 0°C; sepd. by TLC, quenched with acetone, solvent evapd., sepd. by chromy. (silica gel, CH2Cl2/MeOH 98:2);
DOI:10.1021/jp801510b