(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Base Information

Chemical Name:(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)
CAS No.:1023596-52-2
Molecular Formula:C₄₉H₅₀BrN₅Zn
Molecular Weight:854.264
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

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Technology Process of (5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

There total 1 articles about (5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 128-08-5
N-Bromosuccinimide

: 1023596-51-1
(5-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

: 1023596-52-2
(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:: In pyridine; dichloromethane; under N2 or Ar atm.; Zn complex dissolved in CH2Cl2, cooled to 0°C, pyridine syringed, n-bromosuccinimide added, stirred for 30 min at 0°C; sepd. by TLC, quenched with acetone, solvent evapd., sepd. by chromy. (silica gel, CH2Cl2/MeOH 98:2);
DOI:10.1021/jp801510b

Reference yield: 90.0%

: 110-91-8,99108-56-2
morpholine

: 1023596-52-2
(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

: 1023596-54-4
(5-morpholino-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:: In neat (no solvent); under N2 or Ar atm.; Zn complex dissolved in excess C4H8NO, deaerated with N2, heated at 50°C overnight; C2H8NO evapd., residue deposited onto silica gel by vac. evapn.; purified by chromy. (silica gel, CH2Cl2);
DOI:10.1021/jp801510b

Reference yield: 81.0%

: 1023596-52-2
(5-bromo-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

: 109-89-7
diethylamine

: 1023596-59-9
(5-N,N-diethylamino-15-cyano-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:: In diethylamine; under Ar atm.; soln. of Zn complex in C4H10N heated at 50°C overnight; unreacted C4H10N evapd., purified by chromy. (silica gel, CH2Cl2);
DOI:10.1021/jp801510b