(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

Base Information

Chemical Name:(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane
CAS No.:1414941-22-2
Molecular Formula:C₂₂H₃₈O₃Si
Molecular Weight:378.627
Hs Code.:

Synonyms:(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

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Chemical Property of (S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

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Technology Process of (S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

There total 4 articles about (S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 885674-86-2
(S)-1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-ol

: 1414941-22-2
(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

Guidance literature:: Inert atmosphere;
DOI:10.1021/jo302134y

Reference yield:

: 446264-36-4
3-[(4-methoxyphenyl)methoxy]-2,2-dimethyl-propan-1-ol

: 1414941-22-2
(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl; caesium carbonate / Inert atmosphere

2: Inert atmosphere

With (S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl; bis(1,5-cyclooctadiene)diiridium(I) dichloride; caesium carbonate;
DOI:10.1021/jo302134y

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 1414941-22-2
(S)-tert-butyl(1-(4-methoxybenzyloxy)-2,2-dimethylhex-5-en-3-yloxy)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C / Inert atmosphere

1.2: 18 h / 0 - 20 °C / Inert atmosphere

2.1: bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl; caesium carbonate; 4-chloro-3-nitrobenzoate / tetrahydrofuran / 0.5 h / 90 °C / Inert atmosphere; Sealed tube

2.2: 48 h / 120 °C / Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; (S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl; bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium hydride; caesium carbonate; 4-chloro-3-nitrobenzoate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ol3033303