1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

Base Information

Chemical Name:1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene
CAS No.:125364-62-7
Molecular Formula:C₁₈H₃₇ISi₄
Molecular Weight:492.738
Hs Code.:

Synonyms:1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

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Chemical Property of 1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

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Technology Process of 1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

There total 6 articles about 1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 125364-57-0
1-[(Dimethylsilanyl-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-4-methyl-benzene

: 125364-62-7
1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

Guidance literature:: With p-(trimethylsilyl)toluene; iodine; In tetrachloromethane; for 4h; Ambient temperature;
DOI:10.1016/0022-328X(94)88026-3

Reference yield:

: 33664-05-0
(p-Methoxy-phenyl)-dimethyl-fluor-silan

: 125364-62-7
1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

2: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

3: I₂, p-MeC₆H₄SiMe₃ excess / CCl₄

With n-butyllithium; p-(trimethylsilyl)toluene; iodine; In tetrahydrofuran; tetrachloromethane; diethyl ether; pentane;
DOI:10.1039/c39890000595

Reference yield:

: 106-38-7
para-bromotoluene

: 125364-62-7
1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Mg / 1.) ether, 2.) ether, RT, 30 min

2: 40percent aq. HF / ethanol / 4.5 h / Heating

3: 1.) BuLi / 1.) hexane, THF, Et₂O, pentane, -110 deg C, 2 h, 2.) hexane, THF, Et₂O, pentane, -110 deg C - RT, overnight

4: 86 percent / I₂, p-MeC₆H₄SiMe₃ / CCl₄ / 4 h / Ambient temperature

With n-butyllithium; p-(trimethylsilyl)toluene; hydrogen fluoride; iodine; magnesium; In tetrachloromethane; ethanol;
DOI:10.1016/0022-328X(94)88026-3