[(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol

Base Information

• Chemical Name: [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol
• CAS No.: 125364-71-8
• Molecular Formula: C₁₈H₃₈OSi₄
• Molecular Weight: 382.841
• Mol file: 125364-71-8.mol

Synonyms:

Chemical Property of [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol

There total 6 articles about [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(trimethylsilyl)dichloromethane (15951-41-4) → [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol (125364-71-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

2: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

3: I₂, p-MeC₆H₄SiMe₃ excess / CCl₄

4: Et₃N / CDCl₃ / 35 °C

With n-butyllithium; p-(trimethylsilyl)toluene; iodine; triethylamine; In tetrahydrofuran; tetrachloromethane; diethyl ether; chloroform-d1; pentane;

DOI:10.1039/c39890000595

Reference yield:

(p-Methoxy-phenyl)-dimethyl-fluor-silan (33664-05-0) → [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol (125364-71-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

2: 1.) n-BuLi / tetrahydrofuran; diethyl ether; pentane / -110 - 20 °C

3: I₂, p-MeC₆H₄SiMe₃ excess / CCl₄

4: Et₃N / CDCl₃ / 35 °C

With n-butyllithium; p-(trimethylsilyl)toluene; iodine; triethylamine; In tetrahydrofuran; tetrachloromethane; diethyl ether; chloroform-d1; pentane;

DOI:10.1039/c39890000595

Reference yield:

1-[(Dimethylsilanyl-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-4-methyl-benzene (125364-57-0) → [(Dimethyl-p-tolyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanol (125364-71-8)

Guidance literature:

Multi-step reaction with 2 steps

1: I₂, p-MeC₆H₄SiMe₃ excess / CCl₄

2: Et₃N / CDCl₃ / 35 °C

With p-(trimethylsilyl)toluene; iodine; triethylamine; In tetrachloromethane; chloroform-d1;

DOI:10.1039/c39890000595

upstream raw materials:

1,1,1,3',3',3'-hexafluoro-propanol

1-{[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

bis(trimethylsilyl)dichloromethane

(p-Methoxy-phenyl)-dimethyl-fluor-silan

Refernces

• 1、 Eaborn, Colin,Jones, Karen L.,Lickiss, Paul D.. "Anchimeric Assistance by γ-Aryl Groups in Solvolysis of Organosilicon Iodides. Some Remarkably Large Remote Substituent Effects". . p. 595 - 596. Retrieved 2007/10/02.