125364-57-0Relevant articles and documents
Preparation of the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds
Eaborn, Colin,Jones, Karen L.,Lickiss, Paul D.
, p. 35 - 42 (2007/10/02)
The preparations of: (a) the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) (Y=H, p-OMe, p-Me, p-Cl, m-CF3), via the corresponding hydrides; (b) the compounds (Me3Si)2C(SiMe2Ph)(SiMe2X) with X=F, O2CCF3, OMe, N3, NCS and Cl: and (c) the iodide (p-MeC6H4)3CSiMe2I are described. Key words: Silicon; Iodide; Fluoride; Hydride; Trimethylsilyl
Anchimeric Assistance by γ-Aryl Groups in Solvolysis of Organosilicon Iodides. Some Remarkably Large Remote Substituent Effects
Eaborn, Colin,Jones, Karen L.,Lickiss, Paul D.
, p. 595 - 596 (2007/10/02)
The very large spread of rates in reactions of the iodides (Me3Si)2C(SiMe2C6H4X)(SiMe2I) (X = p-OMe, p-Me, H, p-Cl, or m-CF3) with (CF3)2CHOH and CF3CH2OH (the compound with X = p-OMe is 1.9E05 and 6.5E04 times, respectively, as reactive as that with X = m-CF3) is attributed to nucleophilic assistance by the aryl group to the leaving of the I- ion.