Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Base Information

Chemical Name:Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester
CAS No.:182871-44-9
Molecular Formula:C₆₅H₈₀O₁₂Si
Molecular Weight:1081.43
Hs Code.:

Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Synonyms:Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Suppliers and Price of Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

There total 4 articles about Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 142-61-0
Hexanoyl chloride

: 182871-40-5
(2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-ol

: 182871-44-9
Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Guidance literature:: With pyridine; In 1,2-dichloro-ethane; Ambient temperature;
DOI:10.1271/bbb.60.1308

Reference yield:

: 100-39-0
benzyl bromide

: 182871-44-9
Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NaH / 1.) DMF, 0 deg C, 0.5 h, 2.) room temperature, overnight

2: 2>2>PF₆ / tetrahydrofuran / 2 h / Ambient temperature

3: HgO, HgCl₂ / acetone; H₂O / 24 h

4: 92 percent / pyridine / 1,2-dichloro-ethane / Ambient temperature

With pyridine; sodium hydride; mercury dichloride; mercury(II) oxide; (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; In tetrahydrofuran; water; 1,2-dichloro-ethane; acetone;
DOI:10.1271/bbb.60.1308

Reference yield:

: 182871-36-9
{2-[(2R,3R,4S,5R,6R)-6-((2R,3R,4S,5R,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy]-ethyl}-trimethyl-silane

: 182871-44-9
Hexanoic acid (2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 2>2>PF₆ / tetrahydrofuran / 2 h / Ambient temperature

2: HgO, HgCl₂ / acetone; H₂O / 24 h

3: 92 percent / pyridine / 1,2-dichloro-ethane / Ambient temperature

With pyridine; mercury dichloride; mercury(II) oxide; (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; In tetrahydrofuran; water; 1,2-dichloro-ethane; acetone;
DOI:10.1271/bbb.60.1308