(S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON

Base Information

• Chemical Name: (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON
• CAS No.: 217459-11-5
• Molecular Formula: C₂₂H₂₈FeN₂
• Molecular Weight: 376.325

Synonyms:(S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON;(R)-PPY;(S)-PPY;(R)-(+)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL) IRON;(S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON,MIN. 98% (S)-PPY*

Chemical Property of (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON

Chemical Property:

• Melting Point: 163-164°C
• PSA: 15.60000
• LogP: 4.72130

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON

There total 1 articles about (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

N-trimethylsilylpyrrolidine (15097-49-1) + C25H27FeNO3S → Fu's catalyst (217459-10-4,217458-65-6,217459-11-5)

Guidance literature:

With titanium tetrachloride; In tetrahydrofuran; at 20 ℃; for 1.33333h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.5b01044

Reference yield:

(-)-(C5Me5)FeC5H3NC3H(pyrrolidino) (217458-65-6,217459-10-4,217459-11-5) + phenol (108-95-2,27073-41-2) → [Fe(C5(CH3)5)(C5H3C3H2NH(C4H8N))](1+)*C6H5O(1-)=[Fe(C5(CH3)5)(C5H3C3H2NH(C4H8N))]C6H5O

Guidance literature:

In not given; equilibrium reaction;

DOI:10.1021/ja0506152

Reference yield:

silver(I) hexafluorophosphate (26042-63-7) + Fu's catalyst (217459-10-4,217458-65-6,217459-11-5) + Cinnamoyl chloride (102-92-1,17082-09-6) → (+)-[(pyrrolidino)(cinnamoyl)(C8H5N)Fe(C5Me5)]PF6

Guidance literature:

In not given; iron complex reacted with cinnamoyl chloride; exchanged with AgPF6;

DOI:10.1039/b603172b

upstream raw materials:

N-trimethylsilylpyrrolidine

Downstream raw materials:

C₁₂H₁₀NO₄S₂^(1-)*C₃₇H₄₀FFeN₂O⁽¹⁺⁾

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 217459-11-5 (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON

Send

Send

Metric Ton KG G Pound L ML

Send

Send