(8R)-8-tert-butyldiphenylsilyloxydecanol

Base Information

Chemical Name:(8R)-8-tert-butyldiphenylsilyloxydecanol
CAS No.:151985-47-6
Molecular Formula:C₂₆H₄₀O₂Si
Molecular Weight:412.688
Hs Code.:

Synonyms:(8R)-8-tert-butyldiphenylsilyloxydecanol

Suppliers and Price of (8R)-8-tert-butyldiphenylsilyloxydecanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (8R)-8-tert-butyldiphenylsilyloxydecanol

Chemical Property:

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Technology Process of (8R)-8-tert-butyldiphenylsilyloxydecanol

There total 12 articles about (8R)-8-tert-butyldiphenylsilyloxydecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 151985-46-5
(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

: 151985-47-6
(8R)-8-tert-butyldiphenylsilyloxydecanol

Guidance literature:: With hydrogen; palladium carbon;

Reference yield:

: 112-47-0
1,10-Decanediol

: 151985-47-6
(8R)-8-tert-butyldiphenylsilyloxydecanol

Guidance literature:: Multi-step reaction with 12 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

10: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

11: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

12: 79 percent / hydrogen / 10percent palladium carbon

With 1H-imidazole; titanium(IV) isopropylate; lithium aluminium tetrahydride; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; hydrogen; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; palladium carbon; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 144482-51-9
methyl 10-benzyloxydecanoate

: 151985-47-6
(8R)-8-tert-butyldiphenylsilyloxydecanol

Guidance literature:: Multi-step reaction with 9 steps

1: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

2: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

3: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

4: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

5: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

6: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

7: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

8: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

9: 79 percent / hydrogen / 10percent palladium carbon

With 1H-imidazole; titanium(IV) isopropylate; lithium aluminium tetrahydride; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; hydrogen; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; palladium carbon; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;