(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Base Information

Chemical Name:(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane
CAS No.:151985-46-5
Molecular Formula:C₃₃H₄₆O₂Si
Molecular Weight:502.813
Hs Code.:

Synonyms:(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Suppliers and Price of (3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of (3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

There total 12 articles about (3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 151985-45-4
(3R)-10-benzyloxy-3-decanol

: 151985-46-5
(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 24h; Ambient temperature;

Reference yield:

: 112-47-0
1,10-Decanediol

: 151985-46-5
(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Guidance literature:: Multi-step reaction with 11 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

10: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

11: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

With 1H-imidazole; titanium(IV) isopropylate; lithium aluminium tetrahydride; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 100-44-7
benzyl chloride

: 151985-46-5
(3R)-10-benzyloxy-3-(tert-butyldiphenylsilyloxy)decane

Guidance literature:: Multi-step reaction with 11 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

10: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

11: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

With 1H-imidazole; titanium(IV) isopropylate; lithium aluminium tetrahydride; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;