1-[⁷⁷Br]bromo-4-methoxy-benzene

Base Information

Chemical Name:1-[⁷⁷Br]bromo-4-methoxy-benzene
CAS No.:73638-56-9
Molecular Formula:C₇H₇BrO
Molecular Weight:184.132
Hs Code.:

1-[<sup>77</sup><i>Br</i>]bromo-4-methoxy-benzene

Synonyms:1-[⁷⁷Br]bromo-4-methoxy-benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-[⁷⁷Br]bromo-4-methoxy-benzene

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Technology Process of 1-[⁷⁷Br]bromo-4-methoxy-benzene

There total 5 articles about 1-[⁷⁷Br]bromo-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5720-07-0
4-methoxyphenylboronic acid

: 73638-56-9
1-[⁷⁷Br]bromo-4-methoxy-benzene

Guidance literature:: With [⁷⁷Br]bromide; tetrakis(pyridine)copper(II) bis(trifluoromethanesulfonate); In water; dimethyl sulfoxide; at 80 ℃; for 0.333333h; Inert atmosphere; Sealed tube;
DOI:10.1016/j.tetlet.2018.04.024

Reference yield:

: 79-21-0
peracetic acid

: 16759-25-4,24959-67-9
[⁷⁷Br]bromide

: 940-00-1
(4-methoxyphenyl)trimethylstannane

: 73638-55-8
CH₃OC₆H₄⁽⁷⁷⁾Br

: 73638-56-9
1-[⁷⁷Br]bromo-4-methoxy-benzene

Guidance literature:: With dihydrogen peroxide; acetic acid; In acetic acid; addn. of a mixt. of solvent (0.6M MeCO2Na in MeCO2H) and oxidant (in situ generated MeCO3H from 11.4M aq H2O2 and glacial MeCO2H vol. ratio 2:1, kept at room temp. 2 h, prior to application), to dry (77)Br(1-) and tin-compd., stirring, room temp.,30 min; quenching by transferring the vessel contens to 1M aq. NaHSO3 cooled to 0 °C, extn. with CH2Cl2, drying (CaCl2), total yield 28.7%, relative isomeric distribution p:o 90:10%;

Reference yield:

: 79-21-0
peracetic acid

: 16759-25-4,24959-67-9
[⁷⁷Br]bromide

: 14476-81-4
(4-methoxyphenyl)trimethylgermane

: 73638-55-8
CH₃OC₆H₄⁽⁷⁷⁾Br

: 73638-56-9
1-[⁷⁷Br]bromo-4-methoxy-benzene

Guidance literature:: With dihydrogen peroxide; acetic acid; In acetic acid; addn. of a mixt. of solvent (0.6M MeCO2Na in MeCO2H) and oxidant (in situ generated MeCO3H from 11.4M aq H2O2 and glacial MeCO2H vol. ratio 2:1, kept at room temp. 2 h, prior to application), to dry (77)Br(1-) and Ge-compd., stirring, room temp.,30 min; quenching by transferring the vessel contens to 1M aq. NaHSO3 cooled to 0 °C, extn. with CH2Cl2, drying (CaCl2), total yield 53.9%, relative isomeric distribution p:o 92:2%;