3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

Base Information

Chemical Name:3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester
CAS No.:854737-58-9
Molecular Formula:C₃₇H₆₀O₇Si₃
Molecular Weight:701.136
Hs Code.:

3-[4-(<i>tert</i>-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(<i>tert</i>-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

Synonyms:3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

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Chemical Property of 3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

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Technology Process of 3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

There total 7 articles about 3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 854737-54-5
(E)‐3‐(4‐((tert‐butyldimethylsilyl)oxy)‐3‐methoxyphenyl)acrylic acid

: 854737-61-4
1-bromo-2-keto-3-(3,4-di-t-butyldimethylsilyloxy)phenyl propane

: 854737-58-9
3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

Guidance literature:: With sodium hydroxide; tetrabutylammomium bromide; In toluene; at 20 ℃;
DOI:10.1016/j.tet.2005.03.074

Reference yield:

: 854737-59-0
((4-allyl-1,2-phenylene)bis(oxy))bis(tert-butyldimethylsilane)

: 854737-58-9
3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / NBS; H₂O / dimethylsulfoxide / 0 °C

2: 70 percent / Dess-Martin reagent / CH₂Cl₂ / 15 h / 20 °C

3: 57 percent / aq. NaOH; NBu₄Br / toluene / 20 °C

With sodium hydroxide; N-Bromosuccinimide; tetrabutylammomium bromide; water; Dess-Martin periodane; In dichloromethane; dimethyl sulfoxide; toluene; 2: Dess-Martin oxidation;
DOI:10.1016/j.tet.2005.03.074

Reference yield:

: 854737-57-8
(E)‐tert‐butyldimethylsilyl3‐(4‐((tert‐butyldimethylsilyl)oxy)‐3‐methoxyphenyl)acrylate

: 854737-58-9
3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-acrylic acid 3-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2-oxo-propyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / aq. K₂CO₃ / tetrahydrofuran; methanol / 0.5 h / 20 °C

2: 57 percent / aq. NaOH; NBu₄Br / toluene / 20 °C

With sodium hydroxide; tetrabutylammomium bromide; potassium carbonate; In tetrahydrofuran; methanol; toluene;
DOI:10.1016/j.tet.2005.03.074