[Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-)

Base Information

• Chemical Name: [Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-)
• CAS No.: 1219834-08-8
• Molecular Formula: C₁₄₂H₁₄₈CuN₁₄O₁₂Zn*F₆P
• Molecular Weight: 2516.72
• Mol file: 1219834-08-8.mol

Synonyms:[Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-)

Chemical Property of [Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-)

There total 1 articles about [Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂HN₃(C₂H₄O)3C₆H₄)2C₁₂H₆N₂)Cu(C₁₂H₆N₂(C₆H₄(OC₂H₄)2OCH₂)2)]⁽¹⁺⁾*[PF₆]^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + diazidophenanthroline (1173194-17-6) + [Zn(C20H8N4(C6H3(C(CH3)3)2)3C6H3(C2H)2)] (1219834-11-3) + ((C2H4O)2C6H4)NC5H2C2H2C5H2N(C6H4(C2H4O)2)OC2H4O (90030-13-0) → [Zn(C20H8N4(C6H3(C(CH3)3)2)3C6H3(C2HN3(C2H4O)3C6H4)2C12H6N2)Cu(C12H6N2(C6H4(OC2H4)2OCH2)2)](1+)*[PF6](1-) (1219834-08-8)

Guidance literature:

With sodium ascorbate; CuI; DBU; In ethanol; water; (Schlenk techniques); C34H34N2O6 stirred with Cu complex in CH2Cl2/MeCN at room temp. for 30 min, (N3(C2H4O)3C6H4)2C12H6N2 added, stirred at room temp. for 3 h; reacted with CuI, sodium ascorbate, SBP, DBU, Zn complex in H2O/EtOH at room temp. for 12 h; neutralized with aq. HCl, extd. (CH2Cl2), the org. phase washed (H2O), concd., stirred for 3 h with a MeOH soln. of KPF6, evapd. (vac.), extd. (CH2Cl2), filtered, evapd. (vac.), chromd. (SiO2, CH2Cl2/MeOH);

DOI:10.1021/ja910149f

Reference yield: 79.0%

[Zn(C20H8N4(C6H3(C(CH3)3)2)3C6H3(C2HN3(C2H4O)3C6H4)2C12H6N2)Cu(C12H6N2(C6H4(OC2H4)2OCH2)2)](1+)*[PF6](1-) (1219834-08-8) → C34H34N2O6*C108H114N12O6Zn (1279654-41-9)

Guidance literature:

With ammonium hydroxide; In water; acetonitrile; at 20 ℃; for 1h;

DOI:10.1021/ol200304d

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

diazidophenanthroline

[Zn(C₂₀H₈N₄(C₆H₃(C(CH₃)3)2)3C₆H₃(C₂H)2)]

((C₂H₄O)2C₆H₄)NC₅H₂C₂H₂C₅H₂N(C₆H₄(C₂H₄O)2)OC₂H₄O

Downstream raw materials:

C₃₄H₃₄N₂O₆*C₁₀₈H₁₁₄N₁₂O₆Zn