METHYL ACETATE-D3

Base Information

• Chemical Name: METHYL ACETATE-D3
• CAS No.: 21300-54-9
• Molecular Formula: C3H3 D3 O2
• Molecular Weight: 77.0556
• Mol file: 21300-54-9.mol

Synonyms:METHYL ACETATE-D3;MethoxyAcetate-D3

Chemical Property of METHYL ACETATE-D3

Chemical Property:

• PSA: 26.30000
• LogP: 0.17930
• Storage Temp.: 0-6°C

Purity/Quality:

95% ^*data from raw suppliers

MethylAcetate-d3 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Methyl Acetate-d3 (CAS# 21300-54-9) is a useful isotopically labeled research compound.

Technology Process of METHYL ACETATE-D3

There total 2 articles about METHYL ACETATE-D3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetradeuterioacetic acid (1186-52-3) + 4-methoxynitrosobenzene (1516-21-8) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + methyl bisulfate (75-93-4) + methyl trideuteroacetate (21300-54-9) + p-nitrosophenol (104-91-6)

Guidance literature:

With nitrosylsulfuric acid; sulfuric acid; In [D₃]acetonitrile; at 29.84 ℃; Kinetics;

Reference yield:

methane (34557-54-5,27936-85-2) + tetradeuterioacetic acid (1186-52-3) + carbon monoxide (201230-82-2) → deuteromethanol (1455-13-6) + formic acid-d1 (925-94-0) + deuteroacetic acid (758-12-3) + methyl trideuteroacetate (21300-54-9) + <(2)H6>methyl acetate (32113-85-2)

Guidance literature:

With rhodium(III) trichloride hydrate; water-d2; oxygen; sodium chloride; copper(II) oxide; at 95 ℃; for 2h; Autoclave;

DOI:10.1134/S0965544111020022

Reference yield: 79.0%

methyl trideuteroacetate (21300-54-9) → 2,2,2-trideuteroethanol (1759-87-1)

Guidance literature:

With sodium bis(2-methoxyethoxy)aluminum hydride; In tetrahydrofuran; at 65 ℃; for 5h;

DOI:10.1021/jo00079a015

upstream raw materials:

tetradeuterioacetic acid

4-methoxynitrosobenzene

methane

carbon monoxide

Downstream raw materials:

2,2,2-trideuteroethanol