(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Base Information

Chemical Name:(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide
CAS No.:914936-92-8
Molecular Formula:C₃₆H₆₀O₅
Molecular Weight:572.869
Hs Code.:

Synonyms:(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Suppliers and Price of (2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

There total 15 articles about (2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 914936-57-5
(2S)-24-hydroxy-2-(p-methoxybenzyloxy)octacosanolide

: 914936-92-8
(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Guidance literature:: With N-methyl-2-indolinone; tetrapropylammonium perruthennate; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/ol062011o

Reference yield:

: 914936-51-9
(2S)-1-(t-butyldiphenylsiloxy)-2-(p-methoxybenzyloxy)-28-(tetrahydro-2H-pyran-2-yloxy)octacosane-24-ol

: 914936-92-8
(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Guidance literature:: Multi-step reaction with 6 steps

1: 86 percent / p-toluenesulfonic acid monohydrate / CH₂Cl₂ / 2 h / 20 °C

2: 96 percent / acetic acid; TBAF / tetrahydrofuran / 22.5 h / 20 °C

3: TEMPO; sodium chlorite; sodium hypochlorite / acetonitrile; aq. phosphate buffer; H₂O / 8.5 h / 20 °C

4: 262.3 mg / aq. HCl / tetrahydrofuran / 71 h / 20 °C

5: 77 percent / 2-methyl-6-nitrobenzoic anhydride; triethylamine / 4-(dimethylaminopyridine) N-oxide / CH₂Cl₂; tetrahydrofuran / 12 h / 50 °C

6: 94 percent / NMO; TPAP / CH₂Cl₂ / 0.5 h / 0 °C

With hydrogenchloride; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-6-nitrobenzoic anhydride; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; acetic acid; triethylamine; 4-(dimethylamino)pyridine N-oxide; In tetrahydrofuran; phosphate buffer; dichloromethane; water; acetonitrile;
DOI:10.1021/ol062011o

Reference yield:

: 914936-55-3
(2S)-24,28-dihydroxy-2-(p-methoxybenzyloxy)octacosanoic acid

: 914936-92-8
(2S)-2-(p-methoxybenzyloxy)-24-oxooctacosanolide

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / 2-methyl-6-nitrobenzoic anhydride; triethylamine / 4-(dimethylaminopyridine) N-oxide / CH₂Cl₂; tetrahydrofuran / 12 h / 50 °C

2: 94 percent / NMO; TPAP / CH₂Cl₂ / 0.5 h / 0 °C

With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2-methyl-6-nitrobenzoic anhydride; triethylamine; 4-(dimethylamino)pyridine N-oxide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol062011o