η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Base Information

Chemical Name:η5-pentamethylcyclopentadienyl rhodium dicarbonyl
CAS No.:113035-19-1
Molecular Formula:C₁₂H₁₅O₂Rh
Molecular Weight:294.155
Hs Code.:

Synonyms:η5-pentamethylcyclopentadienyl rhodium dicarbonyl

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Chemical Property of η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Chemical Property:

Purity/Quality:

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MSDS Files:: SDS file from LookChem

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Technology Process of η5-pentamethylcyclopentadienyl rhodium dicarbonyl

There total 11 articles about η5-pentamethylcyclopentadienyl rhodium dicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

: RhW⁽⁵⁺⁾*CC₆H₄CH₃^(3-)*3CO*C₅H₅^(1-)*C₅(CH₃)5^(1-)=RhWCC₆H₄CH₃(CO)3C₅H₅C₅(CH₃)5

: 501-65-5
diphenyl acetylene

: 113035-19-1
η5-pentamethylcyclopentadienyl rhodium dicarbonyl

: 95029-83-7
RhC₄(C₆H₅)4COC₅(CH₃)5

: RhWC(C₆H₄CH₃)C(C₆H₅)C(C₆H₅)(CO)2C₅H₅(C₅(CH₃)5)

: 992-04-1
hexaphenylbenzene

Guidance literature:: In toluene; The mixt. of reagents in toluene was heated at 100°C for 5 d (N2atm.), cooling to room temp.;; filtered, chromd. with petroleum ether; elem. anal.;;

Reference yield: 19.0%

: [(η(5)-pentamethylcyclopentadienyl)Rh]2(μ-carbonyl2)

: {CoW(CC₆H₄CH₃)(CO)8}

: 14040-11-0
tungsten hexacarbonyl

: 113035-19-1
η5-pentamethylcyclopentadienyl rhodium dicarbonyl

: {CoRh₂(CC₆H₄CH₃)(CO)4(C₅(CH₃)5)2}

: {tricobalt(μ3-p-tolylmethylidyne)nonacarbonyl}

Guidance literature:: In tetrahydrofuran; mixt. of CoW(CC6H4Me-4)(CO)8 and Rh2(CO)2(C5Me5)2 in THF stirred for 24 h; evapd. in vac., chromd. (Al2O3, light petroleum, CH2Cl2-light petroleum (1:4)); elem. anal.;
DOI:10.1039/DT9870000041

Reference yield:

: 1203571-08-7
H₂RhRe₂Cp*(CO)9

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 113035-19-1
η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Guidance literature:: With CO; 9,10-dihydroanthracene; In toluene; byproducts: H2; under CO (1 atm); at 333.0 K in toluene in the presence of 9,10-dihydroanthracene (5 equivs.); UV spectra studies at 508 nm; Kinetics;
DOI:10.1021/om9007407