η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Base Information

• Chemical Name: η5-pentamethylcyclopentadienyl rhodium dicarbonyl
• CAS No.: 113035-19-1
• Molecular Formula: C₁₂H₁₅O₂Rh
• Molecular Weight: 294.155
• Mol file: 113035-19-1.mol

Synonyms:η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Chemical Property of η5-pentamethylcyclopentadienyl rhodium dicarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of η5-pentamethylcyclopentadienyl rhodium dicarbonyl

There total 11 articles about η5-pentamethylcyclopentadienyl rhodium dicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

RhW(5+)*CC6H4CH3(3-)*3CO*C5H5(1-)*C5(CH3)5(1-)=RhWCC6H4CH3(CO)3C5H5C5(CH3)5 + diphenyl acetylene (501-65-5) → η5-pentamethylcyclopentadienyl rhodium dicarbonyl (113035-19-1) + RhC4(C6H5)4COC5(CH3)5 (95029-83-7) + RhWC(C6H4CH3)C(C6H5)C(C6H5)(CO)2C5H5(C5(CH3)5) + hexaphenylbenzene (992-04-1)

Guidance literature:

In toluene; The mixt. of reagents in toluene was heated at 100°C for 5 d (N2atm.), cooling to room temp.;; filtered, chromd. with petroleum ether; elem. anal.;;

Reference yield: 19.0%

[(η(5)-pentamethylcyclopentadienyl)Rh]2(μ-carbonyl2) + {CoW(CC6H4CH3)(CO)8} → tungsten hexacarbonyl (14040-11-0) + η5-pentamethylcyclopentadienyl rhodium dicarbonyl (113035-19-1) + {CoRh2(CC6H4CH3)(CO)4(C5(CH3)5)2} + {tricobalt(μ3-p-tolylmethylidyne)nonacarbonyl}

Guidance literature:

In tetrahydrofuran; mixt. of CoW(CC6H4Me-4)(CO)8 and Rh2(CO)2(C5Me5)2 in THF stirred for 24 h; evapd. in vac., chromd. (Al2O3, light petroleum, CH2Cl2-light petroleum (1:4)); elem. anal.;

DOI:10.1039/DT9870000041

Reference yield:

H2RhRe2Cp*(CO)9 (1203571-08-7) → decacarbonyldirhenium(0) (14285-68-8) + η5-pentamethylcyclopentadienyl rhodium dicarbonyl (113035-19-1)

Guidance literature:

With CO; 9,10-dihydroanthracene; In toluene; byproducts: H2; under CO (1 atm); at 333.0 K in toluene in the presence of 9,10-dihydroanthracene (5 equivs.); UV spectra studies at 508 nm; Kinetics;

DOI:10.1021/om9007407

upstream raw materials:

triphenylphosphine

(C₅(CH₃)5Rh(CO)(CH₃))2

diphenyl acetylene

[(C5Me5)Rh(μ-carbonylbis(p-tosylazanido))Rh(CO)(C5Me5)]

Downstream raw materials:

(η5-pentamethylcyclopentadienyl)(carbonyl)Rh(η2-C(p-ClC6H4)NOC(O))

(η5-C5Me5)Rh(CO)(C6H11)(H)

(η5-C5Me5)Rh(μ,η2-P2)2Rh(η5-C5Me5)

(cyclopentadienyl)2(dicobalt)(μ3-carbonyl)2(rhodium)(pentamethylcyclopentadienyl)