cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

Base Information

Chemical Name:cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester
CAS No.:382142-90-7
Molecular Formula:C₂₄H₂₂N₂O₄
Molecular Weight:402.45
Hs Code.:

Synonyms:cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

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Chemical Property of cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

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Technology Process of cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

There total 10 articles about cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 623-73-4
diazoacetic acid ethyl ester

: 66607-69-0
4-nitrobenzylidenediphenylmethylamine

: 382142-90-7
cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

: (Z)-3-(Benzhydryl-amino)-3-(4-nitro-phenyl)-acrylic acid ethyl ester

: trans-1-benzhydryl-3-(4-nitrophenyl)-aziridine-2-carboxylic acid ethyl ester

Guidance literature:: triphenylborane; (R)-2,2’-diphenyl-(4-biphenanthrol); In toluene; at 0 - 22 ℃; for 21h;
DOI:10.1021/ol010180x

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 66607-69-0
N-(4-nitrobenzylidene)-1,1-diphenylmethanimine

: cis-1-benzhydryl-(2R)-(4-nitrophenyl)-aziridine-(2R)-carboxylic scid ethyl ester

: 382142-90-7
cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

Guidance literature:: With triphenylborane; water; C₃₂H₂₀Br₂O₂; In toluene; at 20 ℃; for 24h; Reagent/catalyst; Overall yield = 86 percent; enantioselective reaction; Schlenk technique;
DOI:10.1055/s-0039-1690860

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 66607-69-0
4-nitrobenzylidenediphenylmethylamine

: cis-1-benzhydryl-(2R)-(4-nitrophenyl)-aziridine-(2R)-carboxylic scid ethyl ester

: 382142-90-7
cis-1-benzhydryl-(3S)-(4-nitrophenyl)-aziridine-(2S)-carboxylic acid ethyl ester

Guidance literature:: With S-VAPOL-B; In toluene; at 22 ℃; for 24h; Yield given; Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja9905187